Dual-Active-Sites Single-Atom Catalysts for Advanced Applications

Dual-Active-Sites Single-Atom catalysts (DASs SACs) are not only the improvement of SACs but also the expansion of dual-atom catalysts. The DASs SACs contains dual active sites, one of which is a single atomic active site, and the other active site can be a single atom or other type of active site, endowing DASs SACs with excellent catalytic performance and a wide range of applications. The DASs SACs are categorized into seven types, including the neighboring mono metallic DASs SACs, bonded DASs SACs, non-bonded DASs SACs, bridged DASs SACs, asymmetric DASs SACs, metal and nonmetal combined DASs SACs and space separated DASs SACs. Based on the above classification, the general methods for the preparation of DASs SACs are comprehensively described, especially their structural characteristics are discussed in detail. Meanwhile, the in-depth assessments of DASs SACs for variety applications including electrocatalysis, thermocatalysis and photocatalysis are provided, as well as their unique catalytic mechanism are addressed. Moreover, the prospects and challenges for DASs SACs and related applications are highlighted. The authors believe the great expectations for DASs SACs, and this review will provide novel conceptual and methodological perspectives and exciting opportunities for further development and application of DASs SACs.

Automated summary

Dual-Active-Sites Single-Atom catalysts (DASs SACs) are a type of catalysts with dual active sites, including single atomic active sites and other types of active sites. They exhibit excellent catalytic performance and have a wide range of applications. This review comprehensively describes the preparation methods, structural characteristics, and evaluations of DASs SACs in various applications, as well as discusses their unique catalytic mechanisms. The prospects and challenges of DASs SACs and their related applications are also highlighted.