Journal
SEPARATION AND PURIFICATION TECHNOLOGY
Volume 309, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.seppur.2022.122993
Keywords
Azurite; Density functional theory; Adsorption; Catalytic sulfidization
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In this study, microflotation experiments and density functional theory (DFT) calculations were conducted to investigate the influence of ammonium salts on azurite sulfidization. The results showed that the combined treatment of ammonium salt and Na2S resulted in a higher flotation recovery of azurite compared to Na2S treatment alone. DFT calculations demonstrated that HS- could chemically adsorb on the azurite surface and form copper sulfide species. The presence of NH3 enhanced the adsorption of S species and stability of Cu-S species, acting as a catalyst in azurite sulfidization.
In this study, we performed microflotation experiments and density functional theory (DFT) calculations to investigate the effect of ammonium salts on azurite sulfidization. The flotation recovery of azurite with ammonium salt and Na2S treatment was higher than that with Na2S treatment alone. The DFT calculation showed that the S atom in HS- could bond to Cu atoms on the azurite (011) surface, i.e., it chemically adsorbed on the azurite (011) surface to form copper sulfide species. In the presence of NH3, the adsorption energy decreased from-149.42 kJ/mol to-187.26 kJ/mol compared with only HS- adsorption, and the bond length of Cu-S increased from 2.17 A to 2.30 A, indicating enhanced adsorption of the S species. The Cu 3d and S 2p energy-level overlap range became wider, and the formed Cu-S species became complex after catalytic sul-fidization by ammonium salts, enhancing the stability of the Cu-S species. During catalytic sulfidization, NH3 species desorbed from the azurite surface and returned to the solution, so ammonium species acted as a catalyst in azurite sulfidization. This work elucidated the role of ammonium salts in the enhanced sulfidization flotation of azurite at an atomic level and further supplemented our previous experimental statement.
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