Revealing the sorption mechanisms of carbamazepine on pristine and aged microplastics with extended DLVO theory

The co-occurrence of microplastics (MPs) and organic contaminants in aquatic environment can complexify their en-vironmental fate via sorption interactions, especially when the properties of MPs can even vary due to the aging effect. Thus, quantitatively clarifying the sorption mechanisms is required to understand their environmental impacts. This study selected popularly occurring carbamazepine (CBZ) and four types of MPs as model systems, including polyeth-ylene, polyvinyl chloride, polyethylene terephthalate and polystyrene in their pristine and aged forms, to investigate the sorption isotherms, kinetics, and desorption. The variation of MPs during the aging process were analyzed with scanning electron microscopy, contact angle, Fourier transform infrared spectroscopy, and X-ray photoelectron spec-troscopy. It was found that the aging process elevated the sorption capacity and intensified the desorption hysteresis of CBZ on MPs via increasing the surface roughness, decreasing the particle size, and altering the surficial chemistry of all MPs. The extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) theory was innovatively applied hereby to calculate the interfacial free energies and revealed that the hydrophobic interaction was significantly lessened after aging for all MPs with the slightly enhanced van der Waals interaction. Then the total interfacial free energies were dropped down for all MPs, which resulted in their declined specific sorption capacity. This work reveals the sorption mechanisms of CBZ on pristine and aged MPs with XDLVO and provides a useful reference to study the sorption of other neutral organics onto MPs.

Automated summary

This study investigated the sorption mechanisms of the popularly occurring carbamazepine (CBZ) on pristine and aged microplastics (MPs). The aging process of MPs increased their sorption capacity and intensified the desorption hysteresis of CBZ. The XDLVO theory was applied to calculate the interfacial free energies and revealed that the hydrophobic interaction was lessened after aging for all MPs.