Spatial and species-specific responses of biogenic volatile organic compound (BVOC) emissions to elevated ozone from 2014-2020 in China

China suffered from serious and elevated ozone (O3) pollution during 2014-2020. O3 exposure increased with W126, a biologically based cumulative exposure index, at a rate of 1.738 ppm-hr yr-1. MEGAN3.1 was applied to estimate bio-genic volatile organic compound (BVOC) emissions and their response to O3 pollution in China by quantifying species responses to O3 stress. In 2020, China's BVOC emissions were 23.26 Tg when considering the effects of O3 pollution, which was 1.7 % higher than that without O3 stress. Isoprene, monoterpenes, sesquiterpenes, and other VOC emissions changed by -1.0 %, 1.4 %, 15.5 %, and 2.7 %, respectively. The stimulated BVOC emissions were mainly focused on the North China Plain (NCP) and a partial area of the Tibetan Plateau, which increased by >45 %. Changes in monthly emissions differed, with the greatest increase, 181 tons (3.25 %), in August. The seasonal patterns for the impacts of O3 pollution were also distinguished spatially. The elevated O3 exposure caused BVOC emission increases of 104.7 Gg yr-1 during 2014-2020, with isoprene, monoterpenes, sesquiterpenes, and other VOCs contributing -18.6 %, 27.5 %, 40.4 %, and 50.8 %, respectively. The greatest increase in emissions appeared on the NCP and eastern and central China, with annual increases of >100 tons per grid (36 km x 36 km). The interannual variations in BVOC emissions also displayed different seasonal patterns.

Automated summary

China experienced severe ozone pollution from 2014 to 2020, with ozone exposure increasing annually by 1.738 ppm-hr with the W126 index. The MEGAN3.1 model was used to estimate China's biogenic volatile organic compound (BVOC) emissions and their response to ozone pollution. The results showed that China's BVOC emissions in 2020 were 23.26 Tg, 1.7% higher when considering the effects of ozone stress. Different types of BVOC emissions varied in their response to ozone pollution, with changes ranging from -1.0% to 15.5%.