☆ 4.7 Review

Co-free/Co-poor high-Ni cathode for high energy, stable and low-cost lithium-ion batteries

RARE METALS (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Multidisciplinary

Extreme Environmental Thermal Shock Induced Dislocation-Rich Pt Nanoparticles Boosting Hydrogen Evolution Reaction

Siliang Liu et al.

Summary: A non-equilibrium high-temperature thermal-shock method was utilized to induce rich dislocations in Pt nanocrystals, enhancing their catalytic performance. The extreme environmental conditions and ultrafast cooling rate allow for the kinetic freezing of dislocations induced during the crystallization process. This approach presents a novel way to optimize the crystal and electronic structures of nanomaterials for improved catalytic properties.

ADVANCED MATERIALS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Competitive Doping Chemistry for Nickel-Rich Layered Oxide Cathode Materials

Yu-Jie Guo et al.

Summary: Chemical modification of electrode materials by heteroatom dopants is crucial for improving storage performance in rechargeable batteries. This study investigates the competitive doping chemistry of boron and aluminum in nickel-rich cathode materials. The atomic radii difference between B and Al leads to different spatial configurations of bonding with lattice oxygen. The findings provide insights into stabilizing the structural evolution and surface chemistry of the cathode.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Add to Collection

Review Chemistry, Physical

Cobalt-Free Cathode Materials: Families and their Prospects

Hong Zhao et al.

Summary: This review article presents the progress of cobalt-free cathodes made with lithium-rich oxides, nickel-rich layered oxides, and spinel lithium nickel manganese oxide (LNMO). The roles of cobalt are clarified, and the performance and commercialization prospects of these materials are objectively assessed.

ADVANCED ENERGY MATERIALS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Ultrafast Porous Carbon Activation Promises High-Energy Density Supercapacitors

Zhedong Liu et al.

Summary: In this study, a fast high-temperature shock carbonization and activation method was proposed to synthesize activated porous carbons with high specific surface area. The as-prepared supercapacitors based on this method exhibited a high energy density.

SMALL (2022)

Add to Collection

Article Chemistry, Physical

A simple way to induce anode-electrolyte interface engineering through a functional composite separator for zinc-nickel batteries

Zequan Zhao et al.

Summary: By developing a solid-state functionalized composite (FC) separator, the anode-electrolyte interface characteristics of Zn-Ni batteries can be regulated to improve their performance and cycling life. The addition of PAAK helps mitigate hydrogen evolution reaction and improve water retention ability, while reducing the negative effects of oxygen from cathodes. The results demonstrate the large potentials of this new generation of Zn-Ni batteries.

NANO ENERGY (2022)

Add to Collection

Article Chemistry, Physical

In-depth study on diffusion of oxygen vacancies in Li(NixCoyMnz)O2 cathode materials under thermal induction

Zesen Wei et al.

Summary: This study focuses on the secondary particles of different Li(NixCoyMnz)O-2 cathodes, investigating the formation and condensation of oxygen vacancies on the surface, as well as the concentration distribution of oxygen vacancies inside the particles after thermal failure. The results show that increasing the Ni content promotes the diffusion of oxygen vacancies from the surface to the bulk, leading to an increase in oxygen vacancy concentration and the release of more oxygen. When the Ni content reaches 0.8, both the surface layer and bulk of the secondary particles exhibit high oxygen vacancy concentrations, resulting in overall failure. Furthermore, the formation and evolution of intergranular cracks inside the secondary particles depend on the oxygen vacancy concentration gradient.

ENERGY STORAGE MATERIALS (2022)

Add to Collection

Article Chemistry, Physical

Constructing O2/O3 homogeneous hybrid stabilizes Li-rich layered cathodes

Yafen Chen et al.

Summary: A new type of lithium-rich layered oxide with an O2/O3 hybrid structure has been designed, showing greatly improved voltage and capacity stability compared to pure O2 and O3-type LLOs. This novel approach has opened up a new way to reduce capacity and voltage decay in LLOs, promising for the development of high-energy-density LIBs.

ENERGY STORAGE MATERIALS (2022)

Add to Collection

Article Materials Science, Multidisciplinary

Electrochemical characterization of AlPO4 coated LiNi1/3Co1/3Mn1/3O2 cathode materials for high temperature lithium battery application

Jian-Hua Wang et al.

Summary: Aluminum phosphate coating affects the surface structure and electrochemical properties of NCM cathode material, blocking Li+ insertion-extraction process and increasing surface film resistance, while aiding in stabilizing the solid electrolyte interface film and cell resistance.

RARE METALS (2021)

Add to Collection

Article Materials Science, Multidisciplinary

Structural evolution of mesoporous graphene/LiNi1/3Co1/3Mn1/3O2 composite cathode for Li-ion battery

Wen-Jie Liu et al.

Summary: The study found that a bi-material cathode composed of mesoporous graphene and layered LiNi1/3Co1/3Mn1/3O2 (NCM) exhibited better performance at high rates compared to a pure NCM cathode. The improved rate capability of the NCM-G composite electrode is attributed to the highly conductive mesoporous graphene and synergistic effect with NCM material.

RARE METALS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Nickel-Rich Layered Cathode Materials for Lithium-Ion Batteries

Zhengcheng Ye et al.

Summary: This review delves into the electrochemical performance and fading mechanisms of nickel-rich layered transition metal oxide cathodes, summarizes the recent research progress in improving materials through element doping, surface modification, and structure tuning, and proposes new insights to expand the field and promote practical applications of nickel-rich oxides.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Add to Collection

Article Materials Science, Multidisciplinary

TiO2-coated LiNi0.9Co0.08Al0.02O2 cathode materials with enhanced cycle performance for Li-ion batteries

Wei-Wei Li et al.

Summary: In this study, spherical LiNi0.9Co0.08Al0.02O2 powders with 0.4 wt% TiO2 coating layer were prepared by impregnation-hydrolysis method. The TiO2 coating layer effectively improved the cycling performance and stability of the electrode at a high discharge ratio.

RARE METALS (2021)

Add to Collection

Article Materials Science, Multidisciplinary

Suppressing capacity fading and voltage decay of Ni-rich cathode material by dual-ion doping for lithium-ion batteries

Hao Liu et al.

Summary: In this study, a novel strategy was proposed to modify the Ni-rich cathode LiNi(0.8)Co(0.1)Mn(0.1)O(2) with uniform Al and Ti cations co-doping, which effectively stabilized the vulnerable structure and mitigated voltage/capacity attenuation. The modified cathode showed significantly enhanced electrochemical performance, with improved discharge capacity and voltage retention after 200 cycles, even at elevated voltages.

JOURNAL OF MATERIALS SCIENCE (2021)

Add to Collection

Article Chemistry, Physical

Cation-disordered rocksalt-type high-entropy cathodes for Li-ion batteries

Zhengyan Lun et al.

Summary: High-entropy ceramics are solid solutions with compositional flexibility and wide applicability, showing substantial performance improvement in lithium-ion battery cathodes. The high-entropy concept leads to enhancements in energy density and rate capability, especially in cation-disordered rocksalt-type cathodes. High-entropy materials have the potential for various applications and the design of high-entropy solid solutions in the DRX space can further enhance performance in battery electrodes.

NATURE MATERIALS (2021)

Add to Collection

Article Chemistry, Physical

Phase Behavior during Electrochemical Cycling of Ni-Rich Cathode Materials for Li-Ion Batteries

Chao Xu et al.

Summary: The essay explores the rapid performance degradation of layered lithium nickel-rich oxides under specific stress conditions, comparing their structural properties with NMCs and NCAs. It highlights the necessity of reexamining the various high-voltage structural changes in LiNiO2 to aid understanding of accelerated degradation in Ni-rich cathodes.

ADVANCED ENERGY MATERIALS (2021)

Add to Collection

Review Chemistry, Physical

Optimized Ni-Rich NCMA Cathode for Electric Vehicle Batteries

Nam-Yung Park et al.

Summary: The electrochemical and structural stabilities of a conventional NCMA90 cathode and a core-shell with concentration gradient NCMA90 cathode were evaluated, with the latter showing unique microstructure that effectively suppressed microcrack formation and propagation in the highly charged state. These features allowed the core-shell cathode to maintain 90.7% of its initial capacity after 1000 cycles at full depth of discharge, enabling higher electrochemical performance and the development of cost-effective Li-ion batteries.

ADVANCED ENERGY MATERIALS (2021)

Add to Collection

Article Chemistry, Physical

The effect of Ni oxidation state on the crystal structure and electrochemical properties of LiNi0.8Co0.1Mn0.1O2 cathode material for highly reversible lithium storage

Zhaoxin Guo et al.

Summary: Ni-rich LiNi0.8Co0.1Mn0.1O2 single crystals prepared by wet ball-milling and molten-salt methods exhibit superior structural and electrochemical performance compared to traditional polycrystalline materials. The single crystal samples have higher Ni3+ content and better cyclic stability, with a significantly higher capacity retention rate after 300 cycles than polycrystalline samples.

JOURNAL OF ALLOYS AND COMPOUNDS (2021)

Add to Collection

Review Chemistry, Physical

A Review of Degradation Mechanisms and Recent Achievements for Ni-Rich Cathode-Based Li-Ion Batteries

Ming Jiang et al.

Summary: The demand for sustainable energy storage has led to a need for rechargeable lithium-ion batteries with higher specific capacity and safety standards, which has put Ni-rich layered transition metal oxides in the spotlight. While these materials show promise for the next generation of batteries, their instability poses challenges for commercialization. This paper reviews degradation processes in Ni-rich cathode-based LIBs and discusses recent advancements in stabilization strategies for future battery components.

ADVANCED ENERGY MATERIALS (2021)

Add to Collection

Article Chemistry, Physical

A Cobalt- and Manganese-Free High-Nickel Layered Oxide Cathode for Long-Life, Safer Lithium-Ion Batteries

Zehao Cui et al.

Summary: This study presents a cobalt- and manganese-free ultrahigh-nickel LiNi0.93Al0.05Ti0.01Mg0.01O2 (NATM) cathode that demonstrates high capacity retention and enhanced thermal stability, outperforming common high-nickel cathodes.

ADVANCED ENERGY MATERIALS (2021)

Add to Collection

Article Chemistry, Physical

Opportunities and Challenges of Lithium Ion Batteries in Automotive Applications

Alvaro Masias et al.

Summary: Lithium ion batteries (LIBs) have evolved from consumer electronics to powering the automotive sector, meeting the unique requirements of vehicle applications. Automotive-driven battery targets are determined by international research groups and existing electric vehicle performance. Challenges and opportunities in transitioning LIBs from CE to automotive sector are assessed in terms of energy, life, cost, safety, and fast charge capability.

ACS ENERGY LETTERS (2021)

Add to Collection

Article Electrochemistry

Synthesis of Co-Free Ni-Rich Single Crystal Positive Electrode Materials for Lithium Ion Batteries: Part I. Two-Step Lithiation Method for Al- or Mg-Doped LiNiO2

Aaron Liu et al.

Summary: Increasing Ni content in Ni-rich layered positive electrode material improves energy density but reduces cell lifetimes. Single crystalline materials can enhance cell lifetimes by decreasing material degradation. Further research is needed to improve the competitiveness of Mg-containing single crystal materials compared to their polycrystalline counterparts.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

Add to Collection

Article Materials Science, Multidisciplinary

Calcium- and sulfate-functionalized artificial cathode-electrolyte interphases of Ni-rich cathode materials

Kwangeun Jung et al.

Summary: The addition of a calcium sulfate precursor during thermal treatment can create an artificial Ca- and SOx-functionalized CEI layer on the surface of Ni-rich NCM cathode materials, inhibiting electrolyte decomposition and improving cycling retention of lithium-ion batteries. The modified CEI layer effectively controls undesired surface reactions such as electrolyte decomposition and metal dissolution, leading to enhanced performance of the Ni-rich NCM cathodes.

RARE METALS (2021)

Add to Collection

Review Chemistry, Physical

Fundamental and solutions of microcrack in Ni-rich layered oxide cathode materials of lithium-ion batteries

Shouyi Yin et al.

Summary: This review discusses the challenges and solutions of modifying Ni-rich layered cathodes specifically for microcrack failure, including mechanisms of microcrack formation and evolution, recent advances in stabilizing the structure/interface of Ni-rich cathodes, and strategies to mitigate microcracks and improve electrochemical performance. Additionally, outlook and perspectives for practical application of Ni-rich layered cathodes in electric vehicles are provided.

NANO ENERGY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Unraveling TM Migration Mechanisms in LiNi1/3Mn1/3Co1/3O2 by Modeling and Experimental Studies

Hui Wan et al.

Summary: Electrochemical cycling induces transition-metal ion migration and oxygen vacancy formation in layered transition-metal oxides, causing performance decay. This study used ab initio calculations and atomic level imaging to explore the migration mechanisms in LiNi1/3Mn1/3Co1/3O2, revealing favorable pathways for transition-metal migration and the critical role of nickel in stabilizing layered cathodes. Insights from this study may lead to tailored layered cathodes with high structural stability and superior performance.

NANO LETTERS (2021)

Add to Collection

Article Chemistry, Physical

Capacity Fading Mechanisms in Ni-Rich Single-Crystal NCM Cathodes

Hoon-Hee Ryu et al.

Summary: The study found that despite the high resistance to microcracking, the electrochemical performance of single-crystal NCM cathodes is inferior to polycrystalline NCM cathodes in terms of capacity and cycling stability. During cycling, the lithium concentrations in single-crystal NCM cathodes become spatially inhomogeneous, leading to the coexistence of phases with different unit cell dimensions within a single particle, which affects lithium ion diffusion and causes rapid capacity fading.

ACS ENERGY LETTERS (2021)

Add to Collection

Article Materials Science, Multidisciplinary

Development of a LiFePO4-based high power lithium secondary battery for HEVs applications

Long-Zheng Deng et al.

RARE METALS (2020)

Add to Collection

Article Nanoscience & Nanotechnology

Structural and Electrochemical Impacts of Mg/Mn Dual Dopants on the LiNiO2 Cathode in Li-Metal Batteries

Linqin Mu et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

Add to Collection

Editorial Material Multidisciplinary Sciences

Cobalt in lithium-ion batteries

Matthew Li et al.

SCIENCE (2020)

Add to Collection

Article Chemistry, Physical

Cobalt-Free High-Capacity Ni-Rich Layered Li[Ni0.9Mn0.1]O2 Cathode

Assylzat Aishova et al.

ADVANCED ENERGY MATERIALS (2020)

Add to Collection

Review Multidisciplinary Sciences

A reflection on lithium-ion battery cathode chemistry

Arumugam Manthiram

NATURE COMMUNICATIONS (2020)

Add to Collection

Article Chemistry, Physical

Crack-free single-crystalline Ni-rich layered NCM cathode enable superior cycling performance of lithium-ion batteries

Xinming Fan et al.

NANO ENERGY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

High-Nickel NMA: A Cobalt-Free Alternative to NMC and NCA Cathodes for Lithium-Ion Batteries

Wangda Li et al.

ADVANCED MATERIALS (2020)

Add to Collection

Article Electrochemistry

Simultaneous synthesis and synergetic stabilization of Zr-doped and Li6Zr2O7-coated Ni-rich layered cathode for advanced lithium ion batteries

Huiping Yang et al.

ELECTROCHIMICA ACTA (2020)

Add to Collection

Article Chemistry, Physical

High-Temperature Shock Enabled Nanomanufacturing for Energy-Related Applications

Shuming Dou et al.

ADVANCED ENERGY MATERIALS (2020)

Add to Collection

Review Chemistry, Physical

Recent Progress and Perspective of Advanced High-Energy Co-Less Ni-Rich Cathodes for Li-Ion Batteries: Yesterday, Today, and Tomorrow

Ji Ung Choi et al.

ADVANCED ENERGY MATERIALS (2020)

Add to Collection

Article Chemistry, Physical

Confined growth of primary grains towards stabilizing integrated structure of Ni-rich materials

Fanghui Du et al.

JOURNAL OF POWER SOURCES (2020)

Add to Collection

Article Multidisciplinary Sciences

Reversible planar gliding and microcracking in a single-crystalline Ni-rich cathode

Yujing Bi et al.

SCIENCE (2020)

Add to Collection

Article Chemistry, Physical

Correlating the phase evolution and anionic redox in Co-Free Ni-Rich layered oxide cathodes

Ning Li et al.

NANO ENERGY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Dislocation-Strained IrNi Alloy Nanoparticles Driven by Thermal Shock for the Hydrogen Evolution Reaction

Siliang Liu et al.

ADVANCED MATERIALS (2020)

Add to Collection

Article Chemistry, Physical

Problems and their origins of Ni-rich layered oxide cathode materials

Sheng S. Zhang

ENERGY STORAGE MATERIALS (2020)

Add to Collection

Review Chemistry, Physical

Graphitic carbon nitride (g-C3N4)-based nanosized heteroarrays: Promising materials for photoelectrochemical water splitting

Liqun Wang et al.

CARBON ENERGY (2020)

Add to Collection

Article Chemistry, Physical

Microstructure-Controlled Ni-Rich Cathode Material by Microscale Compositional Partition for Next-Generation Electric Vehicles

Un-Hyuck Kim et al.

ADVANCED ENERGY MATERIALS (2019)

Add to Collection

Article Nanoscience & Nanotechnology

Highly Stabilized Ni-Rich Cathode Material with Mo Induced Epitaxially Grown Nanostructured Hybrid Surface for High-Performance Lithium-Ion Batteries

Chunliu Xu et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Add to Collection

Article Nanoscience & Nanotechnology

All Paper-Based Flexible and Wearable Piezoresistive Pressure Sensor

Lei Gao et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Add to Collection

Article Nanoscience & Nanotechnology

Degradation Mechanism of Highly Ni-Rich Li[NixCoyMn1-x-y]O2 Cathodes with x > 0.9

Jae-Hyung Kim et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Add to Collection

Article Chemistry, Physical

A Comprehensive Analysis of the Interphasial and Structural Evolution over Long-Term Cycling of Ultrahigh-Nickel Cathodes in Lithium-Ion Batteries

Jianyu Li et al.

ADVANCED ENERGY MATERIALS (2019)

Add to Collection

Review Chemistry, Multidisciplinary

There and Back Again-The Journey of LiNiO2 as a Cathode Active Material

Matteo Bianchini et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Physical

Structural and Electrochemical Aspects of LiNi0.8Co0.1Mn0.1O2 Cathode Materials Doped by Various Cations

Tina Weigel et al.

ACS ENERGY LETTERS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Simultaneously Dual Modification of Ni-Rich Layered Oxide Cathode for High-Energy Lithium-Ion Batteries

Huiping Yang et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

Add to Collection

Article Electrochemistry

Is Cobalt Needed in Ni-Rich Positive Electrode Materials for Lithium Ion Batteries?

Hongyang Li et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2019)

Add to Collection

Article Chemistry, Physical

Insights into Li/ Ni ordering and surface reconstruction during synthesis of Ni- rich layered oxides

Yandong Duan et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

Add to Collection

Article Electrochemistry

Synthesis of Single Crystal LiNi0.88Co0.09Al0.03O2 with a Two-Step Lithiation Method

Hongyang Li et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Single-particle measurements of electrochemical kinetics in NMC and NCA cathodes for Li-ion batteries

Ping-Chun Tsai et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

Add to Collection

Article Chemistry, Multidisciplinary

An Outlook on Lithium Ion Battery Technology

Arumugam Manthiram

ACS CENTRAL SCIENCE (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Synthetic Control of Kinetic Reaction Pathway and Cationic Ordering in High-Ni Layered Oxide Cathodes

Dawei Wang et al.

ADVANCED MATERIALS (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries

Wen Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Add to Collection

Article Nanoscience & Nanotechnology

A Novel Cobalt-Free, CO2-Stable, and Reduction-Tolerant Dual-Phase Oxygen-Permeable Membrane

Zhongtao Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2013)

Add to Collection

Review Chemistry, Physical

Challenges for Rechargeable Li Batteries

John B. Goodenough et al.

CHEMISTRY OF MATERIALS (2010)

Add to Collection

Article Chemistry, Physical

Cation ordering in layered O3 Li[NixLi1/3-2x/3]Mn2/3-x/3]O2 (0≤x≤1/2) compounds

YS Meng et al.

CHEMISTRY OF MATERIALS (2005)

Add to Collection

Article Chemistry, Physical

Lithium insertion material of LiNi1/2Mn1/2O2 for advanced lithium-ion batteries

Y Makimura et al.

JOURNAL OF POWER SOURCES (2003)

Add to Collection

Article Chemistry, Physical

Electrochemical and thermal behavior of aluminum- and magnesium-doped spherical lithium nickel cobalt mixed oxides Li1-x(Ni1-y-zCoyMz)O2 (M = Al, Mg)

S Albrecht et al.

JOURNAL OF POWER SOURCES (2003)

Add to Collection

Article Electrochemistry

Investigation of the local structure of the LiNi0.5Mn0.5O2 cathode material during electrochemical cycling by X-ray absorption and NMR spectroscopy

WS Yoon et al.

ELECTROCHEMICAL AND SOLID STATE LETTERS (2002)

Add to Collection

Review Electrochemistry

Effects of heteroatoms on electrochemical performance of electrode materials for lithium ion batteries

YP Wu et al.

ELECTROCHIMICA ACTA (2002)

Add to Collection

© Peeref 2019-2024. All rights reserved.