4.7 Article

Transparent nylon 6 nanofibers-reinforced epoxy matrix composites with superior mechanical and thermal properties

Journal

POLYMER TESTING
Volume 122, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.polymertesting.2023.108002

Keywords

Polymer-matrix composites; Electrospun nanofibers; Mechanical properties; Thermal properties; Analytical modelling

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In this study, vacuum infiltration technique was used to fabricate nanofiber-reinforced epoxy matrix composites. The results showed that the reinforcement of nylon 6 nanofibers significantly improved the mechanical and thermal properties of the composites. Although the ultimate tensile strength of N6/YD composite decreased, the N6/YDJR and N6/JR composites showed significant improvement in tensile strength and Young's modulus. The thermogravimetric analysis also showed improved thermal stability of the epoxy resin matrices after the incorporation of nylon 6 nanofibers.
Electrospun nanofibers have been widely researched for their reinforcing ability in polymer composites because of their ultrafine size, high mechanical strength, and ultrahigh surface area. In this study, a vacuum infiltration technique was employed to fabricate electrospun nylon 6 nanofiber-reinforced epoxy matrix composites. It was found that the reinforcement of the epoxy matrices with nylon 6 nanofibers significantly improved the me-chanical and thermal properties of the composites. The ultimate tensile strength of the N6/YD composite decreased compared to that of the reference YD epoxy resin; however, the N6/YDJR and N6/JR epoxy resin composites showed 29% and 500% improvement in the tensile strength, and Young's modulus was enhanced by 20.5%, 49%, and 1700% for the N6/YD, N6/YDJR, and N6/JR composites, respectively. Furthermore, the tensile strength and Young's modulus of the nanocomposites were predicted and validated using the theoretical Hal-pin-Tsai and Takayangi models, while the results of numerical simulations agreed with the experimental mea-surements. Finally, a thermogravimetric analysis showed that the thermal stability of the epoxy resin matrices was significantly improved after the incorporation of nylon 6 nanofibers.

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