Journal
PARTICUOLOGY
Volume 74, Issue -, Pages 141-155Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.partic.2022.05.010
Keywords
ZnFe-LDO/Co3O4; Photoelectrocatalytic; p-n heterojunction; Methylene blue
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ZnFe-layered double oxide (LDO)/cobalt(II,III) oxide (Co3O4) composites were prepared by calcining Co loaded ZnFe-LDO obtained through hydrothermal and microwave hydrothermal methods. The composites exhibited a flower-like structure composed of Co(3)O(4) nanowires and ZnFe-LDO nanosheets. The ZnFe-LDO/Co3O4 composite showed a high degradation efficiency of 93.3% for methylene blue (MB) under visible light and 1.0 V voltage after 3 hours, indicating its potential for organic pollutant removal.
A visible light-active photoelectrocatalyst, ZnFe-layered double oxide (LDO)/cobalt(II,III) oxide (Co3O4) composites were obtained by calcining the Co loaded ZnFe-layered double hydroxide (LDH) prepared by a hydrothermal and microwave hydrothermal method. The morphological studies revealed that the ZnFe-LDO/Co3O4 composites exhibited a flower-like structure comprising Co(3)O(4 )nanowires and ZnFe-LDO nanosheets. Further, when the mass ratio of Co(NO3)(2)center dot 6H(2)O/LDH was 1:1.8 and the calcination temperature was 550 degrees C, the ZnFe-LDO/Co3O4 composite exhibited 93.3% degradation efficiency for methylene blue (MB) at the applied voltage of 1.0 V under visible light after 3 h. Furthermore, the Mott -Schottky model experiments showed that the formation of a p-n heterojunction between ZnFe-LDO and Co3O4 could effectively inhibit the recombination of electrons and holes in the photoelectrocatalytic process. Meanwhile, free radical scavenging experiments showed that the active radicals of ,OH played an important role in the degradation of MB. Therefore, the photoelectrocatalytic effect of ZnFe-LDO/ Co(3)O(4 )provides a simple and effective strategy for the removal of organic pollutants. (C) 2022 Chinese Society of Particuology and Institute of Process Engineering, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
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