4.5 Article

Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C=P Bond Systems

Journal

ORGANOMETALLICS
Volume 42, Issue 7, Pages 505-537

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.2c00379

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This report provides an overview of the use of phosphaalkenes (C=P) in synthesizing various complexes, focusing on the formation of this area of chemistry over the years. It also discusses the coordination types and construction methods of these complexes, with an emphasis on the catalytic properties of phosphaalkene complexes.
This report provides an overview of the use of phosphaalkenes (C=P) in syntheses of various complexes. Going through successive complexes containing the d-block metals, we sought how this area of chemistry was formed over the years. Additionally, this work contains information on the possible coordination types and means of constructing the complexes. In addition, this review reveals the reactivities of phosphaalkene complexes with a strong emphasis on catalytic properties.

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