Pentamethylcyclopentadienyl Metalloradical Iron Complexes Containing Redox Noninnocent ?-Diimine-Type Ligands: Synthesis, Molecular, and Electronic Structures

The synthesis and characterization of pentamethylcy-clopentadienyl iron complexes bearing the redox noninnocent alpha- diimine (N,N '-dimesitylbutane-2,3-diimine, MesDI) and alpha-iminopyr-idine (N-mesityl(pyridin-2-yl)ethanimine MesPI) ligands were explored. One-pot reduction and complexation of the cyclopentadienyl ring was accomplished by treatment of (kappa 2-N,N ')FeCl2 (N,N '= MesDI or MesPI) precursors with [C5Me5]Li. The resulting iron compounds were characterized by paramagnetic 1H NMR spectroscopy, magnetic susceptibility measurements, zero-field 57Fe Mo''ssbauer spectroscopy, low-temperature electron paramagnetic resonance (EPR) spectroscopy, and cyclic voltammetry. The combined spectroscopic, structural, and density functional theory (DFT) computational data supported low-spin iron(III) compounds (SFe = 1/2) with pi-acidic, formally doubly reduced chelating ligands.

Automated summary

The synthesis and characterization of pentamethylcyclopentadienyl iron complexes with redox noninnocent alpha-diimine (MesDI) and alpha-iminopyridine (MesPI) ligands were investigated. Reduction and complexation of the cyclopentadienyl ring were achieved via treatment of (kappa 2-N,N ')FeCl2 (N,N '= MesDI or MesPI) precursors with [C5Me5]Li. The resulting iron compounds were characterized through paramagnetic 1H NMR spectroscopy, magnetic susceptibility measurements, zero-field 57Fe Mössbauer spectroscopy, low-temperature electron paramagnetic resonance (EPR) spectroscopy, and cyclic voltammetry. The spectroscopic, structural, and density functional theory (DFT) computational data confirmed the presence of low-spin iron(III) compounds (SFe = 1/2) with pi-acidic, formally doubly reduced chelating ligands.