Journal
NATURE CHEMISTRY
Volume 15, Issue 4, Pages 446-447Publisher
NATURE PORTFOLIO
DOI: 10.1038/s41557-023-01169-2
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Charge-transfer emission, which is rare for iron coordination complexes, has been observed in an Fe(iii) complex. The emission arises from both metal-to-ligand and ligand-to-metal charge transfer.
Charge-transfer emission of any type is extremely rare for coordination complexes of iron. Now, an Fe(iii) complex has been devised that shows two-colour luminescence arising from dual metal-to-ligand and ligand-to-metal charge-transfer emission.
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