Vanadium MXenes materials for next-generation energy storage devices

Batteries and supercapacitors have emerged as promising candidates for next-generation energy storage technologies. The rapid development of new two-dimensional (2D) electrode materials indicates a new era in energy storage devices. MXenes are a new type of layered 2D transition metal carbides, nitrides, or carbonitrides that have drawn much attention because of their excellent electrical conductivity, electrochemical and hydrophilic properties, large surface area, and attractive topological structure. This review focuses on various synthesis methods to prepare vanadium carbide MXenes with and without etchants like hydrofluoric acid, lithium fluoride, and hydrochloric acid to remove the 'A' layers of the MAX phase. The goal is to demonstrate the utilization of a less toxic etching method to achieve MXenes of comparable properties to those prepared by traditional methods. The influence of intercalation on the effect of high interlayer spacing between the MXene layers and the performance of MXenes as supercapacitor and battery electrodes is also addressed in this review. Lastly, the gaps in the current knowledge for vanadium carbide MXenes in synthesis, scalability, and utilization in more energy storage devices were discussed.

Automated summary

This article reviews the potential of batteries and supercapacitors as next-generation energy storage technologies. The development of new two-dimensional electrode materials, specifically MXenes, is highlighted for their excellent electrical conductivity, electrochemical properties, large surface area, and unique structure. The review focuses on different synthesis methods and the utilization of less toxic etching methods to prepare vanadium carbide MXenes. The influence of intercalation on MXene's performance as supercapacitor and battery electrodes, as well as the gaps in knowledge for vanadium carbide MXenes, are also discussed.