4.8 Article

A Cofacially Stacked Electron-Deficient Small Molecule with a High Electron Mobility of over 10 cm2 V-1 s-1 in Air

Journal

ADVANCED MATERIALS
Volume 27, Issue 48, Pages 8051-8055

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201503803

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Funding

  1. Major State Basic Research Development Program from MOST [2013CB933501]
  2. National Natural Science Foundation of China

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A strong, electron-deficient small molecule, F-4-BDOPV, has a lowest unoccupied molecular orbital (LUMO) level down to -4.44 eV and exhibits cofacial packing in single crystals. These features provide F-4-BDOPV with good ambient stability and large charge-transfer integrals for electrons, leading to a high electron mobility of up to 12.6 cm(2) V-1 s(-1) in air.

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