Journal
MOLECULES
Volume 28, Issue 11, Pages -Publisher
MDPI
DOI: 10.3390/molecules28114488
Keywords
mechanical properties; barrier properties; packaging materials; circular economy
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This study aimed to develop novel chitosan-based packaging materials reinforced with hemp fibers. The addition of hemp fibers significantly improved the mechanical properties of chitosan composites, but had little effect on oxygen barrier properties. These improved biocomposites can be used in food packaging to promote sustainable development and a circular economy.
The use of bioresourced packaging materials is an interesting solution for ecological issues. This work aimed to develop novel chitosan-based packaging materials reinforced with hemp fibers (HF). For this purpose, chitosan (CH) films were filled with 15%, 30%, and 50% (w/w) of two kinds of HF: Untreated fibers cut to 1 mm (UHF) and steam exploded fibers (SEHF). The effect of HF addition and HF treatments on chitosan composites was studied in terms of mechanical properties (tensile strength (TS), elongation at break (EB), and Young's modulus (YM)), barrier properties (water vapor (WVP) and oxygen permeabilities), and thermal properties (glass transition (T-g) and melting temperatures (T-m)). The addition of HF, whether untreated or steam exploded, increased the TS of chitosan composites by 34-65%. WVP was significantly reduced by the addition of HF but no significant change was observed for O-2 barrier property, which was in the range between 0.44 and 0.68 cm(3.)mm/m(2.)d. T-m of the composite films increased from 133 ? for CH films to 171 ? for films filled with 15% SEHF. However, no significant modification was observed for T-g (105-107 ?). The present study showed that the developed biocomposites had improved properties, mainly the mechanical resistance. Their use in food packaging will help industrials the move toward a sustainable development and circular economy.
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