The effect of waste-expanded perlite on alkali activation of ground granulated blast furnace slag

The purpose of this study was to evaluate the possibility of using ground waste-expanded perlite (WP) as a sustainable replacement for ground granulated blast-furnace slag (GGBFS) precursor in alkali-activated systems. The nature and amount of hydration products, microstructure, and compressive strength development were investigated in mixtures where GGBFS was substituted with 10, 20 and 40% by weight of WP and activated by two alkali activators: sodium carbonate and sodium hydroxide. The results show that WP can be successfully used as a partial replacement for GGBFS in alkali-activated materials. Activation by the Na2CO3 solution was more profitable in terms of compressive strength than NaOH, as well as the amount of water bound in the hydration products was higher. Substitution of GGBFS with 20 wt.% of WP activated with sodium carbonate resulted in a compressive strength of 93 MPa at 90 days of hydration while for the equivalent sample activated by sodium hydroxide, 29 MPa. Further incorporation of WP into Na2CO3 activated systems resulted in a reduction in performance development, especially at the early age. In addition to C-S-H, hydrotalcite, and three different types of carbonates in the samples activated by NaOH solution, a rich in sodium C(-N)-S-H was found.

Automated summary

The study evaluated the use of ground waste-expanded perlite (WP) as a sustainable replacement for ground granulated blast-furnace slag (GGBFS) in alkali-activated systems. The results showed that WP can be successfully used as a partial replacement for GGBFS, with activation by sodium carbonate being more beneficial in terms of compressive strength. The incorporation of WP into Na2CO3 activated systems resulted in a reduction in performance development, especially at early ages, and the presence of a sodium-rich C(-N)-S-H.