4.8 Article

3D Scaffolded Nickel-Tin Li-Ion Anodes with Enhanced Cyclability

Journal

ADVANCED MATERIALS
Volume 28, Issue 4, Pages 742-747

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201504780

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Funding

  1. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering through the Frederick Seitz Materials Research Laboratory at the University of Illinois at Urbana-Champaign [DE-FG02-07ER46471]
  2. Nanjing University Creation Talent Program [021314310023]

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A 3D mechanically stable scaffold is shown to accommodate the volume change of a high-specific-capacity nickeltin nanocomposite during operation as a Li-ion battery anode. The nickel-tin anode is supported by an electrochemically inactive conductive scaffold with an engineered free volume and controlled characteristic dimensions, which engender the electrode with significantly improved cyclability.

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