Journal
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
Volume 106, Issue 10, Pages 6098-6105Publisher
WILEY
DOI: 10.1111/jace.19221
Keywords
oxides; perovskites; Ruddlesden-Popper phases; semiconductors; thermoelectric materials
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We studied the impact of varying amounts of CaO layers on the thermoelectric properties of the Ruddlesden-Popper series CaO(CaMnO3)(m) with m = 1, 2, 3, infinity. Dense pellets were obtained through extended ball-milling and hot-pressing, with the sample containing the most CaO layers (m = 1) exhibiting the lowest electrical and thermal conductivity and the highest Seebeck coefficient. Ultimately, the perovskite CaMnO3 (m = infinity) without CaO layers showed the best thermoelectric properties.
We investigated the Ruddlesden-Popper series CaO(CaMnO3)(m) with m = 1, 2, 3, infinity, to study the impact of the varying amounts of CaO layers on their thermoelectric properties. Previous studies showed that highly dense samples are difficult to obtain due to the refractory nature of these materials. In this study, we managed to obtain dense pellets during a classical hot-pressing step, if and only if the samples were subjected to extended ball-milling prior to pressing, resulting in crystallite sizes of 30-35 nm after hot-pressing. The sample with the largest amount of CaO layers (m = 1) had the lowest electrical and thermal conductivity, and the highest Seebeck coefficient, as predicted. Ultimately the perovskite CaMnO3 (m = infinity, no CaO layers) exhibited the best thermoelectric properties.
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