4.6 Article

Self-repairing non-expanded flame-retardant coatings prepared by sol-gel method

Journal

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
Volume 106, Issue 2, Pages 545-552

Publisher

SPRINGER
DOI: 10.1007/s10971-023-06077-y

Keywords

Self-repairing; Flame-retardant coating; Oxygen barrier; Fire-proof; Silica-alumina sol

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The frequent occurrence of building fires has led to a need for flame-retardant coatings. However, existing technologies are expensive, inefficient, and harmful to the environment. A silica-alumina sol has been developed as the substrate for flame-retardant coatings, with boron nitride and glass powders used as fillers to improve the flame retardancy. These hybrid coatings form a high-viscosity liquid-solid phase and can be repaired in high-temperature environments. Experimental results show that the hybrid coating acts as an oxygen barrier, protecting the substrates from fire. Additionally, a carbonous layer is formed on the coating surfaces when exposed to flames, hindering the spread of fire. Due to their low cost, high stability, self-repairing capability, and ease of preparation, these hybrid coatings have great potential for use in fire-proof and flame-retarding applications.
The frequent occurrence of building fires has triggered a compelling need for flame-retardant coatings. However, the existing flame-retardant coating technologies are high-cost, inefficient, and environmentally unfriendly. In this work, a silica-alumina sol has been developed as the substrate of the flame-retardant coatings. Boron nitride (h-BN) and glass powders with low melting temperature are employed as fillers to improve the flame retardancy. This kind of hybrid coatings can form a high-viscosity liquid-solid phase and be re-paired in high-temperature environments. The experimental results indicate that the as-prepared hybrid coating can act as an oxygen barrier to protect the substrates against fire. Besides, a carbonous layer has been formed on the coating surfaces when exposed to flames, which can stem the spread of the flame spread. Due to the low cost, high stability, self-repairing and easy preparation, the self-repairing hybrid coatings show great potential for application in the fields of fire-proof and flame retarding.

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