Journal
CERAMICS INTERNATIONAL
Volume 41, Issue 3, Pages 4822-4828Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2014.12.038
Keywords
Piezoelectric properties; Perovskites; PZT
Categories
Funding
- West Light Foundation of the Chinese Academy of Sciences [A14K001]
- State Key Laboratory of New Ceramics and Fine Processing Tsinghua University [KF201309]
- National Nature Science Foundation of China [51402297]
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xPb(Zn1/3Nb2/3)O-3 (1-x)PbZr0.5Ti0.5O3 (xPZN-(1-x)PZT) (x=0.22-0.36) polycrystalline ceramics with finely varied PZN content were fabricated by a solid-state reaction method. The phase structure, microstructure and temperature dependence of the electrical properties were systematically investigated. The core of the morphotropic phase boundary (MPB) separating the tetragonal from rhombohedral phases located around the region with x=0.26-0.30, identified by XRD measurement and electrical properties. Higher PZN content favored rhombohedral symmetry and stronger relaxor-like characteristics. All compositions demonstrated well-saturated ferroelectric P E loops, and a maximum remnant polarization of P-r similar to 41.83 mu C/cm(2) with a corresponding coercive field E-c similar to 11.3 kV/cm was achieved around MPB. Optimum electrical properties of piezoelectric constant d33-550 pC/N, planar electromechanical coupling coefficient k(p)similar to 0.69, relative dielectric permittivity epsilon(r)similar to 2327 were obtained in the 0.28PZN-0.72PZT composition with a relatively high Curie point of T-c similar to 325 degrees C. This composition also possessed a good electric field-induced-strain property with d*(33) up to 658 pm/V (E= 1 kV/mm), making it promising for application in piezoactuators. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
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