Journal
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
Volume 332, Issue 6, Pages 1901-1907Publisher
SPRINGER
DOI: 10.1007/s10967-023-08860-1
Keywords
Cs+; Ammonium 12-molybdophosphate; Mesoporous silica; Adsorption
Ask authors/readers for more resources
Novel ammonium 12-molybdophosphate loaded mesoporous silica (A-SBA-15) materials were synthesized and used for Cs+ removal. The loading of ammonium 12-molybdophosphate significantly improved Cs+ adsorption capacity. A-SBA-15 showed rapid (20 min) and high Cs+ adsorption (46.8 mg/g). The adsorption mechanism was ion exchange and the process was spontaneous, endothermic, and entropy-increasing.
Novel ammonium 12-molybdophosphate loaded mesoporous silica (A-SBA-15) materials were synthesized and used to remove Cs+ from aqueous solution. The effects of initial Cs+ concentration, contact time, pH value and temperature on Cs+ adsorption were investigated. It was found that Cs+ adsorption capacity was significantly improved by ammonium 12-molybdophosphate loading. The obtained A-SBA-15 exhibited rapid (20 min) and high Cs+ adsorption (46.8 mg/g). The adsorption process can be well fitted by Langmuir and Pseudo-second order models. The adsorption mechanism was ion exchange. Furthermore, the adsorption was spontaneous, endothermic and entropy-increasing. The results demonstrated that A-SBA-15 was a promising Cs+ adsorbent.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available