Journal
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Volume 27, Issue 07N10, Pages 1263-1269Publisher
WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1088424623500797
Keywords
corrole; calixcorrole; isocorrole; isoporphyrin; porphyrin
Categories
Ask authors/readers for more resources
We recently discovered that by using refluxing dichloromethane and extending reaction times, a second molecule of pyrrole can be oxidatively added, resulting in the formation of a novel isoporphyrinoid macrocycle-calixcorrole with yields up to 47%.
We recently reported that DDQ-mediated oxidative coupling of pyrrole to a free-base meso-triarylcorrole in dichloromethane at room temperature results in the near-instantaneous formation of pyrrole-appended isocorroles. Herein we report that the use of refluxing dichloromethane and longer reaction times result in the oxidative addition of a second molecule of pyrrole, affording a novel isoporphyrinoid macrocycle-calixcorrole - in up to 47% yield.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available