Journal
JOURNAL OF PHYSICS D-APPLIED PHYSICS
Volume 56, Issue 34, Pages -Publisher
IOP Publishing Ltd
DOI: 10.1088/1361-6463/accfa5
Keywords
half-metal; ferromagnetic; doping; magnetic anisotropy; first-principles
Categories
Ask authors/readers for more resources
In this study, (C, Mn) co-doped orthorhombic ZnO (termed (C, Mn) @Orth-ZnO) is identified as a room-temperature ferromagnetic half-metal with a magnetic moment of 3 mu (B) per Mn atom. The ferromagnetic interaction in the (C, Mn) @Orth-ZnO system is mainly attributed to the p-d exchange hybridization between C-2p and Mn-3d states. The system also exhibits a large magnetic anisotropy energy and a Curie temperature of 371 K based on mean-field approximation.
Room-temperature ferromagnetic (FM) half-metallic materials are essential for spintronics applications. Here, we find that (C, Mn) co-doped orthorhombic ZnO (termed (C, Mn) @Orth-ZnO) is a room-temperature FM half-metal with a magnetic moment of 3 mu (B) per Mn atom. A detailed investigation of the electronic structure of the (C, Mn) @Orth-ZnO system demonstrates that the FM interaction originates mainly from the p-d exchange hybridization between the C-2p and Mn-3d states. Moreover, the induced extended spin-polarized states of nonmetallic C can mediate the long-range FM exchange interactions beyond the nearest-neighbor situation. The Curie temperature T (C) of the (C, Mn) @Orth-ZnO system is 371 K based on the mean-field approximation. The (C, Mn) @Orth-ZnO system also has a large magnetic anisotropy energy of 0.63 meV, which is mainly attributed to (d(yz), d(z) (2)) orbitals of the Mn atom. Finally, we discuss the influence of carrier concentration and external strain on the stability of the ferromagnetism of the (C, Mn) @Orth-ZnO system. We highlight the application prospects of (C, Mn) @Orth-ZnO in practical spintronic nano-devices.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available