A Self-Stratified Thermally Regenerative Battery Using Nanoprism Cu Covering Ni Electrodes for Low-Grade Waste Heat Recovery

Developing a low-cost and high-performance thermally regenerative battery (TRB) is significant for recovering low-grade waste heat. A self-stratified TRB induced by the density difference between electrolytes is proposed to remove the commercial anion exchange membrane (AEM) and avoid ammonia crossover. The simulation and experiment results show the uneven distribution of NH3, verifying the feasibility of self-stratified electrolytes. For better power generation performance, nanoprism Cu covering Ni electrodes with a high specific surface area and a stable framework are adopted to provide more reaction active sites for fast charge transfer during discharge. A maximum power density (12.7 mW cm-2) and a theoretical heat-to-electricity conversion efficiency of 2.4% (relative to Carnot efficiency of 27.5%) are obtained in the self-stratified TRB employing nanoprism Cu covering Ni electrodes. Moreover, the cost-effectiveness, simple structure, and sustainable discharge operation indicate that it will be a potential choice for energy conversion from low-grade heat.

Automated summary

Developing a low-cost and high-performance thermally regenerative battery (TRB) is significant for recovering low-grade waste heat. A self-stratified TRB induced by the density difference between electrolytes is proposed, which avoids the use of commercial anion exchange membrane and prevents ammonia crossover. The adoption of nanoprism Cu covering Ni electrodes with a high specific surface area and stable framework in the self-stratified TRB results in a maximum power density of 12.7 mW cm-2 and a theoretical heat-to-electricity conversion efficiency of 2.4%.