Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 127, Issue 22, Pages 10499-10507Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.3c00686
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The combination of operando DRIFTS measurement and DFT calculation reveals the counterintuitive HCHO sensing mechanism of In4Sn3O12. At the optimum temperature of 200 degrees C, HCHO undergoes partial oxidation to formate (or HCOOH) with medium activation energy (0.43-0.68 eV) and sufficient electron donation effect, resulting in the generation of sensor signal. The Sn(3a)-connected O acts as the active site, playing crucial roles in both HCHO adsorption and partial oxidation.
The combination of operando Diffuse Reflectance InfraredFourierTransform Spectroscopy measurement and Density Functional Theory calculationreveals the counterintuitive HCHO sensing mechanism of In4Sn3O12. It is merely partial oxidation of HCHOinto formate (or HCOOH) with medium activation energy (0.43-0.68eV) and sufficient electron donation effect that is responsible forthe sensor signal at the optimum temperature of 200 degrees C. The Sn(3a)-connected O is the active site and plays key roles in both HCHOadsorption and partial oxidation.
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