Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 88, Issue 13, Pages 7929-7939Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c02738
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Benzo[h]imidazo[1,2-a]quinolines and1,2a-diazadibenzo[cd,f]azulenes were synthesized via regioselectivecycloisomerization reactions starting from a common intermediate. The choice of Bronsted acid and solvent significantly influenced the selectivity of the reactions. The optical and electrochemical properties of the products were characterized using UV/vis, fluorescence, and cyclovoltammetric measurements, which were further supported by density functional theory calculations.
Benzo[h]imidazo[1,2-a]quinolines and 1,2a-diazadibenzo[cd,f]azuleneswere prepared from a common intermediate by regioselective cycloisomerizationreactions. The selectivity was controlled by the choice of Bronstedacid and solvent. The optical and electrochemical properties of theproducts were studied by UV/vis, fluorescence, and cyclovoltammetricmeasurements. The experimental results were complemented by densityfunctional theory calculations.
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