Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 88, Issue 13, Pages 8360-8368Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.3c00380
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A 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene(4-CzIPN)-photocatalyzed cascade arylation/cyclization reaction of 2-isocyanobiaryls and iodoniumylides was established for the synthesis of 6-arylated phenanthridines. This is the first example of employing iodonium ylides as aryl radical sources in a visible-light-induced radical cascade cyclization reaction.
A 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene(4-CzIPN)-photocatalyzedcascade arylation/cyclization reaction of 2-isocyanobiaryls and iodoniumylides was established for the synthesis of 6-arylated phenanthridines.This is the first example of employing iodonium ylides as aryl radicalsources in a visible-light-induced radical cascade cyclization reaction.
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