4.7 Article

Phase transition characteristics of heavy oil-viscosity reducer-water emulsion systems

Journal

JOURNAL OF MOLECULAR LIQUIDS
Volume 379, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.molliq.2023.121638

Keywords

Heavy oil; Viscosity reducer; Phase transition; Emulsion

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This study investigates the phase transition characteristics of heavy oil-viscosity reducer-water emulsion system. It was found that an oil-in-water (O/W) emulsion occurs when the VR concentration is greater than 0.3 wt%, the oil-water ratio is lower than 1:1, and the salinity is less than 10,000 mg/L. On the other hand, a water-in-oil emulsion is formed when the VR concentration is less than 0.3 wt%, the oil-water ratio is higher than 1:1, and the salinity is higher than 10,000 mg/L. These findings provide valuable insights for adjusting the parameters of heavy oil recovery using VR.
Heavy oil reservoirs can be feasibly developed using viscosity reducer (VR), by which the heavy oil is emulsified to form a less viscous oil-in-water (O/W) emulsion. As the formed emulsion is unstable, we studied the phase transition characteristics of the heavy oil-VR-water emulsion system. First, we used an emulsifier to prepare the heavy oil-VR-water emulsion system. The microscopic properties of the emulsion system were investigated using a microfluidic test system and laser particle size analyzer after the emulsion system reached phase equilibrium. To measure the conductivity of the emulsion system, a conductivity meter was used. The effects of different concentrations of VR, salinities, and oil-water ratios on the type of emulsion were determined. The results indicated that an O/W emulsion occurred when the VR concentration was greater than 0.3 wt%, the oil-water ratio was lower than 1:1, and the salinity was less than 10,000 mg/L. Higher VR concentrations reduced the droplet size to the micron scale. A water-in -oil emulsion was formed when the VR concentration was less than 0.3 wt%, the oil-water ratio was higher than 1:1, and the salinity was higher than 10,000 mg/L. The parameters of heavy oil recovery using VR can be adjusted upon obtaining the critical values of the factors influencing the change in the type of emulsion. These findings can help better understand the phase transition characteristics of heavy oil-VR-water emulsion systems.(c) 2023 Elsevier B.V. All rights reserved.

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