4.7 Article

High mass-loading and binder-free flexible vanadium-based oxide cathode for zinc-ion battery via a bridge of MXene

Journal

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
Volume 143, Issue -, Pages 84-92

Publisher

JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2022.09.042

Keywords

Zinc -ion batteries; Vanadium oxide; MXene bridge; High mass -loading; Flexible electrode

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Flexible zinc-ion batteries (ZIBs) with high safety and low production cost are ideal power sources for portable devices. The low mass-loading and limited areal capacity of the cathode materials are the main challenges for practical ZIBs. This study introduces a binder-free flexible vanadium oxide (MCV@CC) cathode with high mass-loading and large areal capacity, achieved through the bridge effect of MXene. The binder-free cathode reduces the electrochemically inactive weight and enhances the energy density of ZIBs. The MCV@CC cathode demonstrates desirable areal capacity and cycling stability, and the reaction mechanism is found to be based on reversible Zn2+/H+ (de)intercalation in the vanadium oxide interlayer. The use of the bridge effect strategy in constructing high mass-loading flexible electrodes provides insights for ZIBs applications.
Flexible zinc-ion batteries (ZIBs) are promising power sources for portable devices due to their high safety and low production cost. However, the low mass-loading and limited areal capacity of cathode materials are the major problems blocking the practicability of ZIBs. Herein, a high mass-loading and binder-free flexible vanadium oxide (MCV@CC) cathode with a large areal capacity was fabricated via the bridge effect of MXene. The functional MXene bridge induces the growth of the vanadium oxide active layer on the carbon cloth (CC) flexible substrate. The binder-free cathode can reduce the electrochemically inactive weight of the whole electrode, which enhances the energy density of ZIBs. Consequently, the MCV@CC cathode (mass-loading of similar to 7 mg cm-2) delivers a desirable areal capacity (2.36 mAh cm-2) and good cycling stability (capacity retention of 86.1% after 1200 cycles at 10 mA cm-2). Moreover, several ex -situ characterization results indicate that the reaction mechanism upon battery cycling is based on the reversible Zn2 +/H+ (de)intercalation in the vanadium oxide interlayer. Furthermore, the assembled quasi -solid-state MCV@CC//Zn flexible battery exhibits decent performance at different bending states. Such a bridge effect strategy sheds light on the construction of high mass-loading flexible electrodes for ZIBs applications. (c) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

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