Structural features of 18R-type long-period stacking ordered phase in Mg85Zn6Y9 alloy and the Ni doping effect on its hydrogen storage properties

Magnesium-based alloys with 18R-type long-period stacking ordered (LPSO) structures have attracted wide attention for structural and functional applications. To understand hydrogen storage properties of 18R phase, the Mg85Zn6Y9 alloy with 94 wt.% of 18R-type LPSO phase is prepared in this work. The 18R phase has a layered structure where Y-Zn-Mg and Mg layers alternately stack along the c-axis. In the Y-Zn-Mg layers, Y, Zn and partial Mg sites are co-occupied by Y and Mg, Zn and Mg, and Mg and Zn/Y atoms, respectively. Thus the 18R phase is easily decomposed into alpha-MgH2, gamma-MgH2, YH2, YH3, C14-type Laves phase MgZn2 and minor CsCl-type Y(Mg,Zn) during ball milling under hydrogen atmosphere. Af-ter further hydrogen absorption-desorption cycling, Y(Mg,Zn) disappears gradually and C14 phase trans-forms into C15-type Laves phase. By contrast, the Mg85Zn6Y9 alloy has better hydrogen storage kinetics and cycle durability than pure Mg because of the catalytic effect of YH2 /YH3 on hydrogen absorption -desorption and inhibition role of Laves phase in Mg crystallite growth. Moreover, the introduction of Ni into Mg85Zn6Y9 sample leads to a further decrease in activation energy of hydrogen desorption from 106.39 to 96.78 kJ mol -1 due to the formation of Mg2Ni. This work not only provides new insights into structural features and hydrogen storage characteristics of 18R phase but offers an effective method for improving hydrogen storage properties.(c) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

Automated summary

In this work, the hydrogen storage properties of the Mg85Zn6Y9 alloy with 94 wt.% of 18R-type LPSO phase were investigated. The 18R phase easily decomposes into various phases during ball milling under a hydrogen atmosphere. The Mg85Zn6Y9 alloy exhibits better hydrogen storage kinetics and cycle durability compared to pure Mg due to the catalytic effect of YH2/YH3 and the inhibition role of the Laves phase.