4.6 Article

Mechanical and ablation properties of 3D orthogonal woven C/C-SiC composite based on high-solid-loading slurry impregnation

Journal

JOURNAL OF MATERIALS SCIENCE
Volume 58, Issue 22, Pages 9196-9209

Publisher

SPRINGER
DOI: 10.1007/s10853-023-08616-y

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A three-dimensional orthogonal woven C/C-SiC composite was prepared by slurry impregnation, precursor infiltration, and pyrolysis. The composite exhibited excellent mechanical properties and ablation performance. The passive oxidation of SiC and pitting caused by SiO2 contributed to the good ablation performance.
A three-dimensional orthogonal woven C/C-SiC composite was successfully prepared by high-solid-loading slurry impregnation combined with precursor infiltration and pyrolysis. The microstructure, mechanical properties and ablation behavior of the C/C-SiC composite were investigated. The slurry impregnation and the precursor infiltration and pyrolysis acted as fast filling and supplementary densification, respectively. Based on a three-dimensional orthogonal woven C/C preform, the C/C-SiC composite had excellent mechanical properties with bending strength and fracture toughness of 364.46 and 22.86 MPa center dot m(1/2). The mass and linear ablation rates of the C/C-SiC composite were 3.21 mg/s and 4.93 mu m/s, respectively, after ablation under an oxyacetylene flame for 300 s. The good ablation performance was attributed to the passive oxidation of SiC at high temperature and high oxygen partial pressure, and the pitting caused by SiO2 accelerated the failure of carbon fibers.

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