Journal
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 128, Issue 3, Pages 1825-1832Publisher
SPRINGER
DOI: 10.1007/s10973-016-6040-3
Keywords
Pyrolysis; Biomass; Kinetic analysis; Pseudocomponent; Sinusoidally modulated temperature method
Funding
- National Natural Science Foundation of China [51406220]
- Shanxi Province Coal-based Key Technology Research and Development Program [MD 2014-03]
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The pyrolysis kinetic analysis of the three pseudocomponents of biomass, namely cellulose, hemicellulose and lignin, were investigated using a thermogravimetric (TG) analyzer. The multi-peaks method was used to fit the Gaussian distribution model of DTG curves. The activation energies of three pseudocomponents pyrolysis were evaluated using sinusoidally modulated temperature method. The results showed that the multi-peaks methods can fit the DTG curves of cellulose, hemicellulose and lignin successfully. There was only one reaction stage for the pyrolysis of cellulose and hemicelluloses. There were two reaction stages for the pyrolysis of lignin. The average E was 112.6, 162.8 and 156.8 kJ mol(-1) for cellulose, hemicellulose and lignin, respectively.
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