Journal
JOURNAL OF FLUID MECHANICS
Volume 957, Issue -, Pages -Publisher
CAMBRIDGE UNIV PRESS
DOI: 10.1017/jfm.2022.1067
Keywords
general fluid mechanics; computational methods
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This study simulates the diffusiophoresis process in non-electrolyte phoretic systems with consideration of certain constraints, and investigates the equilibrium and fully developed states. The simulation results reveal the dependence of equilibrium states on solute diffusivity and the reference solute concentration. The study also explores the effect of solute-interface interactions on diffusiophoresis and demonstrates particle separation through diffusiophoresis.
Diffusiophoresis takes place when a particle in solution moves due to the presence of a solute concentration gradient. This phenomenon is often studied under some simplifying assumptions, such as negligible diffusive layer thickness or infinite diffusion coefficient. In this work we simulate diffusiophoresis without these simplifications. The goal of this numerical study is to investigate equilibrium and fully developed states of non-electrolyte phoretic systems. Simulation results show that equilibrium states depend on solute diffusivity and on a reference solute concentration far from the particle. An expression is regressed that gives the (equilibrium) diffusiophoretic velocity as a function of solute concentration gradient, solute diffusion coefficient and the reference solute concentration far from the particle. A different set of results reveals that the state of phoretic systems does not depend on the initial conditions when time goes to infinity. This motivates the definition of fully developed states, designating those systems whose properties no longer depend on initial conditions. Apart from these findings, this work also depicts the effect of solute-interface interactions on diffusiophoresis. Simulation results for two solid particles with different interaction potentials are used to illustrate particle separation via diffusiophoresis. Finally, values of particle mobility are calculated for different solute-interface attraction strengths. These results are compared with another work in the literature, which studies polymer diffusiophoresis via molecular simulations (Ram & iacute;rez-Hinestrosa et al., J. Chem. Phys., vol. 152, 2020, p. 164901).
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