Journal
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 127, Issue 3, Pages 2263-2271Publisher
SPRINGER
DOI: 10.1007/s10973-016-5672-7
Keywords
Copolymers; Spectroscopic studies; Thermal properties; Bulk polymerization
Funding
- People Programme (Marie Curie Actions) of the European Union's Seventh Framework Programme FP7/under REA [608382]
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In this study, 2,4,6-trichlorophenyl methacrylate (TClPhMA) was synthesized by the reaction of methacryloyl chloride with 2,4,6-trichlorophenol in the ice bath condition. The obtained monomer was extracted by chloroform and purified on a chromatography column. In order to confirm the chemical structure of the new compound, spectroscopic studies (ATR-FTIR, H-1 NMR, C-13 NMR and GC-MS) were undertaken. The obtained TClPhMA was copolymerized with commercially available monomers such as methyl methacrylate, styrene, 1,4-divinylbenzene and 2-hydroxymethyl methacrylate. The copolymers were obtained by bulk polymerization in which benzoyl peroxide was used as a free radical initiator. The thermal properties of the copolymers were investigated by differential scanning calorimetry and thermogravimetry.
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