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Progress on metal-support interactions in Pd-based catalysts for automobile emission control

Journal

JOURNAL OF ENVIRONMENTAL SCIENCES
Volume 125, Issue -, Pages 401-426

Publisher

SCIENCE PRESS
DOI: 10.1016/j.jes.2022.01.011

Keywords

Palladium; Three-way catalysts (TWCs); Metal-support interaction; Oxide supports

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Metal-support interactions (MSI) are crucial for the performance of Pd-based three-way catalysts, and further research on MSI would contribute to the development of catalysts for automobile exhaust control.
The interactions between metals and oxide supports, so-called metal-support interactions (MSI), are of great importance in heterogeneous catalysis. Pd-based automotive exhaust control catalysts, especially Pd-based three-way catalysts (TWCs), have received considerable research attention owing to its prominent oxidation activity of HCs/CO, as well as excellent thermal stability. For Pd-based TWCs, the dispersion, chemical state and thermal stability of Pd species, which are crucial to the catalytic performance, are closely associated with interactions between metal nanoparticles and their supporting matrix. Progress on the research about MSI and utilization of MSI in advanced Pd-based three-way catalysts are reviewed here. Along with the development of advanced synthesis approaches and engine control technology, the study on MSI would play a notable role in further development of catalysts for automobile exhaust control. (c) 2022 The Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V.

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