Related references
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Article
Electrochemistry
Fangfang Fan et al.
Summary: This research presents a facile strategy to construct a nanomaterial with controllable composition and structure for oxygen reduction and evolution reactions in rechargeable Zn-air batteries. The nanomaterial consists of Co, CoxP, and a hollow N-doped carbon shell. The relationship between activity and shell thickness was studied. By adjusting the phosphorous content, the nanomaterial showed superior bifunctional oxygen electrocatalytic activity. In addition, it exhibited excellent performance in a practical Zn-air battery.
ELECTROCHIMICA ACTA
(2023)
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Hongjiao Huang et al.
Summary: By coating and etching metal clusters, the activity of metal single-atoms can be optimized through electron redistribution and modulation of M-N bond lengths, resulting in enhanced ORR activity. This strategy shows great potential in energy storage devices.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
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Chenhui Zhou et al.
Summary: A Mn-doped RuO2 bimetallic oxide with atomic-scale dispersion of Mn atoms exhibits remarkable activity and super durability for both ORR and OER, providing a new catalyst design strategy for Zn-air batteries.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Article
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Bing Zhang et al.
Summary: This study successfully prepared an anemone-like CoP@CoOOH core-shell heterojunction catalyst using oxygen-vacancy and core-shell heterojunction engineering strategy, which exhibited excellent HER and OER activities in both neutral and alkaline media. The core-shell heterojunction accelerated the catalytic kinetics, while oxygen-vacancies reduced the kinetic barrier, ultimately enhancing the OER performance.
Review
Chemistry, Multidisciplinary
Bin Wu et al.
Summary: Nitrogen-doped carbons are a rapidly growing class of materials for oxygen electrocatalysis, offering low cost, environmental friendliness, excellent conductivity, and scalable synthesis. They have the potential to replace precious metal-based electrocatalysts and reduce costs in energy conversion and storage systems.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
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Li Song et al.
Summary: The integration of heteroatom doped carbon nanotubes and cobalt phosphide through simultaneous phosphorization and carbonization method demonstrates an effective bifuctional oxygen reduction and evolution catalysis. The in-situ generated Co2P weakens the catalytic graphitization effect of metallic Co during carbonization, leading to the formation of more pyridinic-N species. The resultant Co2P/doped-CNTs catalyst shows outstanding ORR and OER performances, making it a promising air-cathode catalyst for rechargeable zinc-air batteries.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
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Zhenfei Liu et al.
Summary: The Co@NPC/C-MWCNTs hybrid material exhibits excellent oxygen reduction reaction (ORR) performance with high catalytic activity, effective four-electron transfer, and superior formate-tolerance ability. The flexibility and stability of the membraneless flexible direct formate fuel cell (DFFC) using Co@NPC/C-MWCNTs as the cathode catalyst make it a promising candidate for powering low-power electronics.
CHEMICAL ENGINEERING JOURNAL
(2022)
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Chemistry, Multidisciplinary
Yu-Ping Ku et al.
Summary: This study investigates the dissolution of Fe-N-C electrocatalysts under conditions similar to fuel cells and reveals a linear correlation between the charge passed through the electrode and the amount of Fe dissolved. The findings suggest an interconnection between the oxygen reduction reaction and Fe dissolution, and introduce a simple metric to report the stability of the material.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
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Chemistry, Physical
Nengfei Yu et al.
Summary: This article reports a novel, efficient and low-cost bifunctional oxygen electrocatalyst, which is prepared by anchoring atomically dispersed cobalt atoms on nitrogen-doped porous graphene nanosheets and forming a unique Co-N-4-C structure. The catalyst exhibits excellent electrical conductivity, large surface area and three-dimensional hierarchically porous architecture, providing more active sites to accelerate the kinetics of oxygen reduction reaction and oxygen evolution reaction, as well as facilitating charge transport to reduce diffusion barrier. The catalyst demonstrates superior bifunctional activity and durability compared to noble-metal catalysts, showing promise for energy conversion and storage applications.
Article
Chemistry, Physical
Yatian Zhang et al.
Summary: A unique Mg-decorated three-dimensionally ordered mesoporous (3DOM) Co3O4 electrocatalyst is developed as a low-cost and high-efficiency cathodic material for zinc-air batteries. The modulation of electronic structure and bonding configuration of the Co sites effectively enhances the interaction with oxygen species and improves the activity of the catalyst. The tailored 3D interpenetrating porous structure provides large diffusion channels for oxygen species and highly accessible active sites. The zinc-air battery assembled with this catalyst exhibits high power density and long-term cyclability, outperforming commercial noble-metal based catalysts.
Article
Materials Science, Multidisciplinary
Yu Ma et al.
Summary: This study reports the design of a freestanding bifunctional cathode for zinc-air batteries. The cathode is composed of tiny Co nanoparticles embedded in N-doped carbon nanofiber aerogels, offering uniform dispersion, balanced distribution, hierarchically porous structure, and moderate defects. The as-fabricated cathodes exhibit excellent performance, with low oxygen electrode potential and overpotential, high peak power density, large specific capacity, and remarkable stability. Moreover, the as-assembled quasi-solid-state zinc-air batteries show outstanding mechanical flexibility and cycle performance.
ENERGY & ENVIRONMENTAL MATERIALS
(2022)
Review
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Chandni Das et al.
Summary: The identification of hydrogen as a green fuel has sparked interest in sustainable development and research in water electrolysis. Transition metal non-oxides (TMNOs) have emerged as efficient electrocatalysts, outperforming transition metal oxides (TMOs). TMNOs can effectively catalyze the oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and oxygen reduction reaction (ORR), making them potential replacements for conventional noble metal electrocatalysts. This review discusses the crystal structure, synthesis strategies, and properties of nanostructured TMNOs, as well as the challenges and future prospects of energy conversion and storage materials in advancing the hydrogen economy.
Article
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Wen Wen Xie et al.
Summary: Hierarchical hollow frameworks of dual-sided Fe/Fe3C@N-doped carbon nanotubes were formed through a template-engaged method. The electrocatalyst exhibited enhanced oxygen electrocatalytic activity and stability, providing high performance for Zn-air batteries.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2022)
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Chemistry, Inorganic & Nuclear
Ghulam Yasin et al.
Summary: The cathode process, oxygen reduction reaction (ORR), is crucial for producing green and reliable energy from the reorganization of chemical bonds in fuel cells. However, the efficiency of ORR is limited due to various factors, including the linearity of ORR intermediates binding energies and the influences of the watery environment on active sites. Understanding the interface structures and interfacial interactions during ORR is important for developing efficient electrocatalysts.
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(2022)
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Multidisciplinary Sciences
Luqi Wang et al.
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NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Physical
Chuanlan Xu et al.
Summary: This study proposes an endogenous regulation strategy to enhance the oxygen reduction reaction (ORR) performance of single-atom Fe catalysts. Theoretical calculations show that the endogenous Fe3C nanostructures can activate the atomically dispersed Fe-N4 sites, promoting the ORR catalytic performance. This work is significant for boosting the ORR performance of single-atom catalysts in electrochemical energy systems.
ENERGY STORAGE MATERIALS
(2022)
Article
Green & Sustainable Science & Technology
Gokul Raj et al.
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SUSTAINABLE MATERIALS AND TECHNOLOGIES
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Wen Wen Xie et al.
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(2022)
Review
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Riyue Ge et al.
Summary: Molybdenum carbide-based nanomaterials show competitive performances for energy conversion applications due to their unique physicochemical properties. Surface and interface engineering holds promise for constructing efficient MoxC-based electrocatalysts, but challenges like low electronic conductivity, catalytic efficiency, and structural instability need to be addressed.
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Chemistry, Physical
Teng Wang et al.
Summary: In this study, a highly efficient bifunctional electrocatalyst for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) was developed via a simple and cost-effective method involving dopamine polymerization triggered by zeolitic imidazolate framework (ZIF). The resulting Co and N codoped cage-in-cage porous carbon exhibited superior ORR and OER performances, attributed to simultaneous compositional and structural tailoring enabled by the judicious polymer coating.
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Chemistry, Physical
Tengteng Gu et al.
Summary: A novel noble-metal-free trifunctional heterostructure electrocatalyst Mo2C/Co@NC was successfully fabricated using a metal-organic framework (MOF)-based approach. The improved structural features and strong interfacial coupling effects between Mo2C nanosheets and Co@NC polyhedron significantly enhanced the intrinsic activities and accessible active sites, boosting the electrocatalytic performance for HER, OER and ORR. This study provides a new protocol for constructing high-performance electrocatalysts for water splitting and zinc-air batteries.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Review
Chemistry, Physical
Minghe Luo et al.
Summary: This review emphasizes the importance of heterostructured air electrocatalysts developed through interface engineering in enhancing oxygen electrocatalysis performance, and highlights the potential relationship between interface chemistry and oxygen electrocatalysis kinetics.
ADVANCED ENERGY MATERIALS
(2021)
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Yu-Lin Wu et al.
Summary: This study has developed an ordered macroporous superstructure of N-doped nanoporous carbon anchored with ultrafine Ru nanoclusters for electrocatalytic micro/nanoreactors, showing unparalleled performance for pH-universal hydrogen evolution reactions. The superstructure exhibits significantly higher mass activity compared to the benchmark Pt/C, with remarkably low overpotential and ultra-high turnover frequency in alkaline solution.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Physical
Gaopeng Liu et al.
Summary: The cobalt nanoparticles and molybdenum carbide heterostructures anchored N doped carbon composite shows remarkable performance for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) in overall water splitting. By combining Mo2C's outstanding HER performance and Co nanoparticles' excellent OER activity, the optimized electrocatalyst achieves low cell voltage and stable long-time operation, providing insights into the design of outstanding non-noble metal bifunctional electrocatalysts for overall water splitting.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Chemistry, Physical
Jiannan Cai et al.
Summary: A bifunctional catalyst, Co@WC1-x/NCNTs composite, with superior electrocatalytic performance for oxygen reduction and oxygen evolution reactions has been synthesized. It also shows ultra-high power density and stability in zinc-air batteries, offering a meaningful strategy for exploring efficient bifunctional catalysts in this application.
JOURNAL OF POWER SOURCES
(2021)
Article
Chemistry, Multidisciplinary
Hongwei Zhang et al.
Summary: In this study, an ultrastable FeCo bifunctional oxygen electrocatalyst on Se-doped CNTs was synthesized, showing excellent oxygen reduction and oxygen evolution reaction activities, surpassing commercial catalysts. The FeCo/Se-CNT catalyst demonstrated extraordinary stability and superior performance in rechargeable Zn-air batteries.
Article
Chemistry, Applied
Yuzhi Li et al.
Summary: This study presents a novel water splitting electrocatalyst constructed through controlled carbonization and phosphorization of a Prussian blue analogue. The FeCo-FeCoP@C@NCCs material exhibits stronger electronic interaction and hollow structure, requiring small overpotentials for hydrogen and oxygen evolution, as well as demonstrating impressive durability in overall water splitting applications.
JOURNAL OF ENERGY CHEMISTRY
(2021)
Article
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Yanli Niu et al.
Summary: This study demonstrates a method to construct efficient Co/MnO heterointerface electrocatalysts by a coordination construction-thermal decomposition strategy, which shows outstanding oxygen electrocatalytic activities and durability. The study also reveals that the Co/MnO heterostructure plays a crucial role in optimizing the adsorption energy for oxygen-containing intermediates in OER and ORR.
ENERGY STORAGE MATERIALS
(2021)
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Liming Deng et al.
Summary: Designing a well-defined metal-support interfacial bond is an effective strategy to optimize the intrinsic activity of noble metals, but it is also challenging. The developed quantum-sized metal nanoparticles anchored on nickel metal-organic framework nanohybrids demonstrate excellent hydrogen evolution reaction (HER) activity at all pH values, surpassing even commercial Pt/C and recent noble-metal catalysts. The interfacial-bond-induced electron redistribution plays a crucial role in enhancing the reaction kinetics and overall performance of the hybrids.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
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Engineering, Environmental
Zejun Zhao et al.
Summary: A sacrifice-template strategy combined with carbonization treatment was used to fabricate hollow Mo-W-polydopamine hybrid nanotubes embedded with ultrasmall Mo-W bimetallic carbides for boosting electrocatalytic hydrogen evolution and lithium ions storage. The resulting MoxW2xC/N, P-codoped CNTs exhibited outstanding electrocatalytic activity and lithium storage performance, making it a promising material for both applications.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Physical
Xin Ye et al.
Summary: A simple one-step method was developed to prepare CoNi/MoC-NP-CTS nanoparticles with high catalytic activity, showing excellent performance in metal-air batteries. This work opens a new avenue for designing and constructing advanced non-precious-metal electrocatalysts in metal-air batteries.
JOURNAL OF POWER SOURCES
(2021)
Review
Chemistry, Physical
Yasir Arafat et al.
Summary: Secondary Zn-air batteries are considered as a promising power source for the future due to their low cost, high energy density, eco-friendliness, and high safety. However, their widespread implementation is hindered by the slow oxygen redox reactions. Developing cost-effective and highly efficient air electrodes to replace precious metals is highly challenging but desired.
ADVANCED ENERGY MATERIALS
(2021)
Review
Chemistry, Physical
Wendan Xue et al.
Summary: The development of stable, adequate, and cost-effective catalysts for fuel cells is urgent. Heteroatom-doped carbons and metal-organic frameworks (MOFs) are promising materials for electrocatalytic oxygen reduction reaction (ORR). Component manipulation, morphological control, and structural engineering play important roles in improving the ORR performance of these materials.
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Chemistry, Multidisciplinary
Qi Lu et al.
Summary: The study successfully designed and fabricated a high-efficiency bifunctional electrocatalyst using high-temperature shock technology, with high activities for both oxygen reduction and oxygen evolution reactions. The composite structure of the catalyst utilizes the synergistic effect and intrinsic activity of the Co-N-C moiety, as well as the porous structure of carbon nanofibers.
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Chemistry, Multidisciplinary
Linlin Li et al.
Summary: Metal hydroxides@MXene hybrids were introduced as efficient electrocatalysts for the alkaline HER, showing Pt-like catalytic activity and excellent stability. The interfacial electronic coupling between transition-metal hydroxides and MXene nanosheets plays a crucial role in optimizing the adsorption energy of water and hydrogen. This study highlights the great potential of interfacial electronic coupling in developing advanced electrocatalysts for applications in energy-related fields.
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Review
Chemistry, Physical
Fan Yang et al.
Summary: This paper reviews the recent progress of Co-based electrocatalysts in ZABs, including cobalt chalcogenides, cobalt oxides, Co-based layered double hydroxides (LDHs), and Co-N-C structures. Synthesis approaches, modification strategies, and structure-performance relationships are discussed in each category. An overview of current achievements, challenges, and future prospects is provided.
Review
Chemistry, Multidisciplinary
Chuangang Hu et al.
Summary: Since the discovery of N-doped carbon nanotubes as the first carbon-based metal-free electrocatalyst for oxygen reduction reaction in 2009, C-MFECs have shown multifunctional electrocatalytic activities for various reactions. While some C-MFECs have demonstrated comparable or superior performance to those based on noble metals, further research and development are required for practical applications in energy conversion and storage. The structure-property relationship and mechanistic understanding of C-MFECs, along with current challenges and future perspectives, are key areas of focus for advancing this field.
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