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SCIENCE OF THE TOTAL ENVIRONMENT
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Yaobin Ding et al.
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APPLIED CATALYSIS B-ENVIRONMENTAL
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CHEMICAL ENGINEERING JOURNAL
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CHEMICAL ENGINEERING JOURNAL
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CHEMICAL ENGINEERING JOURNAL
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Zeyu Guan et al.
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SEPARATION AND PURIFICATION TECHNOLOGY
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Ping Qi et al.
Summary: This review introduces the current research status of single atom catalysts, the characterization techniques for dispersion states of active sites, and future research directions, analyzing the advantages and limitations of each technique.
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Green & Sustainable Science & Technology
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Jongkook Hwang
Summary: Single atom catalysts (SACs) have emerged as a promising class of catalysts that combine the advantages of both heterogeneous and homogeneous catalysts, offering high atom utilization efficiency, unprecedentedly high catalytic activity and selectivity. Metal-organic framework (MOF)-derived synthesis routes, with their high structural/chemical tunability, large surface area and high porosity, have shown great potential for preparing stable SACs without particle aggregation and sintering. This review comprehensively summarizes the synthesis strategies for MOF-derived SACs, categorizing them into five classes and discussing the current challenges and future opportunities in this field.
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Jun Liang et al.
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ENVIRONMENTAL SCIENCE & TECHNOLOGY
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Wu Yang et al.
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JOURNAL OF COLLOID AND INTERFACE SCIENCE
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Bingkun Huang et al.
Summary: This review summarizes the emerging synthetic and characterization strategies of Single-atom catalysts (SACs) and analyzes their development tendency in the environmental field and advanced oxidation processes (AOPs). The advantages of SACs in generating reactive oxygen species and constructive opinions for their stability and activity are discussed. Lastly, the opportunities and challenges faced by SACs and its future development direction in the AOPs catalytic field are proposed.
JOURNAL OF HAZARDOUS MATERIALS
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Zhe Zhou et al.
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Xing Ma et al.
Summary: A general and facile strategy for the construction of high-loading single-atom catalysts with a tunable coordination microenvironment has been developed based on metal-organic frameworks. The well-accessible and atomically dispersed metal sites possess close proximity to photosensitive units, greatly accelerating charge transfer and promoting photocatalysis. The optimized Ni-1-S/MOF with a unique Ni(I) microenvironment presents excellent photocatalytic H-2 production activity, surpassing other counterparts.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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Review
Chemistry, Physical
Panpan Zhang et al.
Summary: This review highlights recent advances in theoretical simulations for persulfate-based advanced oxidation processes, focusing on catalyst properties, persulfate activation mechanism, and degradation mechanism of organic contaminants. The study also discusses descriptors in computational studies and structure-performance relationships within the field. Challenges and future research focuses of DFT simulations in PS-AOPs are proposed, including evaluation of catalyst properties, elucidation of activation mechanisms, and rational design of on-demand catalysts.
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Engineering, Environmental
Yurou Zhou et al.
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Review
Chemistry, Multidisciplinary
Yanan Shang et al.
Summary: Carbon-based single atom catalysts show high performances and efficiency in environmental catalysis, but there is a lack of comprehensive research on their catalytic sites and mechanisms in advanced oxidation processes, which is necessary for further exploration.
CHEMICAL SOCIETY REVIEWS
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Usha Jinendra et al.
Summary: Fe3O4@CFR@GO and Fe3O4@CFR@TiO2 nanocomposites were successfully fabricated by hydrothermal method and showed high efficiency in adsorptive degradation of Evans blue dye, with maximum adsorption capacities of 0.1435 mg/g and 9.345 mg/g respectively. Kinetic studies revealed that the adsorption of Evans blue dye followed a pseudo-first-order kinetic model.
Article
Chemistry, Physical
Jiaquan Li et al.
Summary: This study presents a controllable preparation of Co-based single-atom catalyst anchored on a graphitic carbon nitride support, which is successfully applied for the selective oxidation of ethylbenzene to derive acetophenone with over 95% conversion and selectivity under highly selective and environmentally friendly conditions. The oxidation of ethylbenzene into acetophenone is attributed to the oxidative radicals generated from the decomposition of PMS via electron transfer, highlighting the potential of this catalyst in the oxidation of hydrocarbons.
JOURNAL OF MATERIALS CHEMISTRY A
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