4.6 Article

Comparison of properties of carbon reinforced plastic obtained on the basis of semicrystalline polyimide R-BAPB and other high-temperature-resistant thermoplastic matrices

Journal

JOURNAL OF APPLIED POLYMER SCIENCE
Volume 140, Issue 33, Pages -

Publisher

WILEY
DOI: 10.1002/app.54283

Keywords

carbon fiber reinforced plastics; heat resistant thermoplastic; interlayer fracture toughness; semicrystalline polyimide; thermal and mechanical properties

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In this study, the properties of carbon fiber reinforced plastics (CFRPs) based on semicrystalline polyimide R-BAPB were compared with highly heat-resistant thermoplastic polymers, Ultem-1000 and PEEK. The CFRPs based on PEEK and R-BAPB exhibited the highest thermal stability and heat resistance. Among all the studied CFRPs, the highest interlaminar fracture toughness was observed in CFRPs based on semicrystalline R-BAPB.
Heat resistant thermoplastic matrices offer potential advantages over thermoset polymers and represent a promising alternative in advanced composite applications. In the present work, the properties of carbon fiber reinforced plastics (CFRPs) based on the developed semicrystalline polyimide R-BAPB were studied and compared with those of highly heat-resistant thermoplastic polymers such as amorphous polyetherimide Ultem-1000 and semicrystalline polyetherketone PEEK. To obtain CFRP, an approach was used basing on the uniform distribution of polymer powders on continuous carbon fibers by electrostatic spraying followed by their impregnation in heated calenders and hot pressing. The thermal and thermomechanical properties of CFRPs based on mentioned above polymers were studied. The effect of temperature on the mechanical behavior of CFRPs, including flexural properties and interlaminar fracture toughness G1C, was investigated as well. CFRPs based on PEEK and R-BAPB are found to have the highest thermal stability and heat resistance. The maximum flexural strength, which practically does not change in a wide temperature range from -50 to 180 degrees C, is observed for CFRP based on R-BAPB polyimide. Among the investigated CFRPs, the highest value of interlaminar fracture toughness is shown by CFRPs based on semicrystalline R-BAPB.

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