Mixed ionic-electronic transport in Na2O doped glassy electrolytes: Promising candidate for new generation sodium ion battery electrolytes

In the present communication, newly developed glassy electrolytes, Na2O-ZnO-CdO, have been considered to discuss their electrical transport behavior at ambient temperature. The AC conductivity and relaxation behavior of them have been studied in the light of Almond-West formalism. The electrical conductivity (mixed conduction) is found to be a function of frequency as well as temperature. In the low-frequency range, it shows a flat conductivity owing to the diffusional motion of Na+ ions, whereas at high frequency, the conductivity shows dispersion. The DC conductivity ( s dc ) and hopping frequency have been computed from the best fitted plots of experimental data. The AC conductivity at different concentrations and a constant temperature has been reported. The variation in the conductivity data with reciprocal temperatures indicates the dynamical behavior of charge carriers via hopping conduction in sodium oxide glassy systems. Mixed conduction in the present system may be dominated by polaron hopping in the samples with a lower Na2O content with a percolation type of motion of the electron/polaron. On the other hand, three-dimensional Na+ motion is the dominating charge carrier for the samples with a higher Na2O content. A negligible small difference in pathways in the I-V characteristics in both the directions should make the present system a promising candidate for the new generation battery electrolyte.

Automated summary

In this study, the electrical transport behavior of newly developed Na2O-ZnO-CdO glassy electrolytes at ambient temperature was investigated. The AC conductivity and relaxation behavior were analyzed using the Almond-West formalism. Both frequency and temperature were found to affect the electrical conductivity, which exhibited a flat pattern at low frequencies and dispersion at high frequencies. The DC conductivity and hopping frequency were calculated based on the best fitted experimental data. The study also revealed the dynamical behavior of charge carriers in sodium oxide glassy systems through hopping conduction.