Intrinsic imperfect and zero thermal quenching property for a novel ?-NaYF4:Eu3+,Tb3+red-light emitting phosphor for NUV LEDs

Despite long-term development of LEDs, problems urgent to resolve is still existing. The most outstanding problem to tackle is luminescent stability at high temperature working situation. In this study, a novel type of beta-NaYF4 based phosphor incorporated with Eu3+ and Tb3+ is reported. A series of beta-NaYF4:0.065Eu3+,xTb3+ (x = 0.001, 0.002, 0.003, 0.004, 0.005) phosphors were synthesized by hydrothermal method. The sample beta-NaYF4:0.065Eu3+,0.002Tb3+ possesses optimal luminescent property at room temperature. The mechanism of energy transfer from Tb3+ to Eu3+ ion is quadrupole-quadrupole interactions. The sample beta-NaYF4:0.065Eu3+,0.002Tb3+ demonstrates zero thermal quenching (ZTQ) property at 303 K to 383 K. According to XRD and XPS characterizations, nonequivalent replacement between intrinsic ion Na+ and Y3+ were discovered, which finally leads to production of crystal defects. According to electron paramagnetic resonance (EPR) characterization and density functional theory (DFT) calculation, the type of crystal defect of beta-NaYF4:0.065Eu3+,0.002Tb3+ is confirmed to be VY vacancies which are the predominant defect of crystal. The depths and densities of defects were calculated according to data of thermoluminescence spectra (TL spectra). Crystal defects play the role of electrons traps that could store electrons. Electrons stored in traps will be excited to excitation state of Eu3+ under the thermal stimulation to offset undesirable impact of thermal quenching (TQ), which leads to ZTQ property of the sample beta-NaYF4:0.065Eu3+,0.002Tb3+. The CRI and CCT of fabricated WLED are 3830 K and 84.1, respectively. (c) 2023 Elsevier B.V. All rights reserved.

Automated summary

Despite long-term development of LEDs, the urgent problem of luminescent stability at high temperature working situation still exists. In this study, a novel type of β-NaYF4-based phosphor incorporated with Eu3+ and Tb3+ was reported. Samples of β-NaYF4:0.065Eu3+,0.002Tb3+ were synthesized and showed optimal luminescent properties at room temperature.