4.7 Article

Ag@Fe3O4 nanoparticles decorated NrGO nanocomposite for supercapacitor application

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 941, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2023.169024

Keywords

Graphene; Core-shell nanoparticles; Supercapacitors; Nanocomposite

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In this study, Ag@Fe3O4 core@shell nanoparticles decorated nitrogen doped reduced graphene oxide (NrGO) were successfully obtained with a facile and simple method. The ternary nanocomposite exhibited a specific capacitance of 212.2 F/g and retained 77% of its specific capacitance after 10,000 cycles, indicating great potential as an electrode material for supercapacitor applications.
There is still a great need for production and design of electrode materials with superior electrochemical properties for supercapacitor application. Nanocomposites containing graphene-based metal-metal oxide nanostructures are promising electrode materials because of their high conductivity, excellent surface properties, and effective charge storage with both EDLC and pseudocapacitance mechanisms. In this study, Ag@Fe3O4 core@shell nanoparticles decorated nitrogen doped reduced graphene oxide (NrGO) was ob-tained with a facile and simple method. On the surface of NrGO nanosheets, Ag nanoparticles were found to be coated with Fe3O4 nanoparticles with a particle size of 5-12 nm. The electrochemical measurements of NrGO-Ag@Fe3O4 nanocomposite were carried out in a two-electrode cell. The ternary nanocomposite ex-hibited 212.2 F/g specific capacitance at a current density of 1 A/g, as well as high cyclic stability, the NrGO-Ag@Fe3O4 nanocomposite retained 77 % of its specific capacitance after 10,000 cycles. The Ag@Fe3O4 de-corated NrGO nanocomposite indicates great potential as an electrode material for supercapacitor appli-cations.(c) 2023 Elsevier B.V. All rights reserved.

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