☆ 4.7 Article

Highly electrochemically stable Li2B12H12-Al2O3 nanocomposite electrolyte enabling A 3.8 V room-temperature all-solid-state Li-ion battery

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Physical

Ionic conductivity in complex metal hydride-based nanocomposite materials: The impact of nanostructuring and nanocomposite formation

Laura M. de Kort et al.

Summary: Complex metal hydrides have gained attention as solid electrolytes for all-solid-state batteries due to their desirable properties. This review highlights two strategies, nanostructuring and nanocomposite formation, to enhance the room temperature conductivity of complex metal hydrides. The achievements in nanostructured complex metal hydride-based ion conductors and complex metal hydride/metal oxide nanocomposite ion conductors are summarized, and the trends and challenges in their preparation are discussed. Furthermore, the reported all-solid-state batteries based on complex metal hydride nanocomposite electrolytes are highlighted. Future research directions and perspectives for improving metal hydride ion conductors and metal hydride-based all-solid-state batteries are proposed.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Add to Collection

Article Chemistry, Physical

Study on the suppression of lithium dendrites based on solid electrolyte Li7La3Zr2O12 with annealing treatment of Al interlayer

Yanhua Zhang et al.

Summary: The growth of lithium dendrites in LLZO solid electrolytes has been a major obstacle to the development of all-solid-state lithium batteries. In this study, two different interlayers, one electronically conductive (Al) and one electronically non-conductive (Al2O3), were constructed at the Li/LLZO interface to explore the mechanism behind lithium dendrite growth. The results showed that the battery with an annealed Al2O3 interlayer exhibited good cycle stability, with no internal short circuit observed after 1000 cycles, while the battery with an Al interlayer experienced internal short circuit after only 95 cycles. It was found that the reaction between the Al2O3 interlayer and Li+ during the charge and discharge process formed a Li-Al-O compound, which acted as a Li+ conductive layer to promote lithium deposition and prevent dendritic growth. In contrast, the presence of the Al interlayer allowed electron transport to LLZO, leading to lithium dendritic growth.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Add to Collection

Article Chemistry, Physical

Effect of Nb5+ doping on the microstructure and conductivity of Li1.125Ta0.875Zr0.125SiO5 electrolyte

Yanzhi Zhang et al.

Summary: The microstructure and electrochemical properties of Li1.125Ta0.875-xNbxZr0.125SiO5 ceramics prepared via the solid-phase reaction method were investigated. The conductivity of the ceramics increased and then decreased as the Nb doping concentration increased. Nb doping at 0.1875 mol facilitated the fusion and connection between grains, reducing the number of grain boundaries and increasing the conductivity. The structural distortion caused by the discrepancy in ionic radii of Ta5+ and Nb5+ allowed for more accommodation of Li ions and promoted Li+ diffusion, reducing the energy potential barrier for ion transport. The Li1.125Ta0.6875Nb0.1875Zr0.125SiO5 ceramic exhibited the highest conductivity, making it a potential candidate for all-solid-state batteries.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Add to Collection

Article Materials Science, Multidisciplinary

Modulating composite polymer electrolyte by lithium closo-borohydride achieves highly stable solid-state battery at 25°C

Kepan Bao et al.

Summary: Rational composite design is crucial for developing high-performance composite polymer electrolytes for solid-state lithium metal batteries. The introduction of Li closo-borohydride into the polymer electrolyte has shown to greatly enhance Li+ conduction properties, while density functional theory calculations have revealed the mechanism behind this improvement. In addition, the novel composite polymer electrolyte exhibits excellent electrochemical, thermal, and mechanical stability, making it highly compatible with various electrode materials.

SCIENCE CHINA-MATERIALS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Closo-Borate Gel Polymer Electrolyte with Remarkable Electrochemical Stability and a Wide Operating Temperature Window

Matthew Green et al.

Summary: This study demonstrates the robust and stable nature of a closo-borate based gel polymer electrolyte (GPE), which enables outstanding electrochemical stability and capacity retention upon extensive cycling. The GPE has a high ionic conductivity and can be used with a lithium metal electrode for extended cycling. It can also be incorporated into a flexible battery.

ADVANCED SCIENCE (2022)

Add to Collection

Article Chemistry, Physical

Enhancement of lithium argyrodite interface stability through MoO2 substitution and its application in lithium solid state batteries

Yuvaraj Subramanian et al.

Summary: This study improved the interface stability of Li-argyrodites through metal and oxygen substitution, and evaluated their structural and electrochemical performances. The results showed that MoO2 substitution can enhance critical current density and ionic conductivity.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Methylamine Lithium Borohydride as Electrolyte for All-Solid-State Batteries

Jakob B. Grinderslev et al.

Summary: This article reports the discovery of a new mono-methylamine lithium borohydride with very fast Li+ conductivity at room temperature. The material exhibits a unique two-dimensional layered structure, which enables fast Li-ionic conduction through large voids in between the layers. The material has negligible electronic conductivity and good electrochemical stability.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Add to Collection

Article Chemistry, Physical

Li10Sn0.95P2S11.9-xOx: A new sulfide solid electrolyte for all-solid-state batteries

Dongxu Liu et al.

Summary: This study investigates the doping of oxygen in Li10SnP2S12 electrolyte using solid-phase sintering method to improve the ionic conductivity and stability to lithium and air. The doped electrolyte shows enhanced conductivity, improved stability, and good cycling performance in all-solid-state batteries.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Add to Collection

Article Chemistry, Physical

Exceptionally high sodium ion conductivity and enhanced air stability in Na3SbS4 via germanium doping

Liangliang Yu et al.

Summary: In addition to widely used lithium-ion secondary batteries, solid-state batteries (SSBs) are gaining increasing attention in the research on future-generation energy storage systems. This study obtained a novel sodium-ion solid-state electrolyte, Na3.1Ge0.1Sb0.9S4, through a solid-state chemical reaction, which exhibited good ionic conductivity and stability.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Add to Collection

Article Chemistry, Physical

The power of multifunctional metal hydrides: A key enabler beyond hydrogen storage

Muhammad Saad Salman et al.

Summary: Metal hydrides (MHs) exhibit distinct properties that enable a range of applications, including thermal compression, sensors, and catalysis. While nickel-metal hydride batteries are currently the main market application, new battery concepts and hydride-based fuel cells are emerging. MHs also have important applications in hydrogen compression, heat pumps, catalysis, and chemical analysis.

JOURNAL OF ALLOYS AND COMPOUNDS (2022)

Add to Collection

Article Chemistry, Physical

Fast magnesium ion conducting isopropylamine magnesium borohydride enhanced by hydrophobic interactions

Lasse G. Kristensen et al.

Summary: In this study, the structure, ionic conductivity, and thermal properties of isopropylamine magnesium borohydride based composites were investigated. Three new compounds were discovered and the relationship between high ionic conductivity and hydrophobic interactions was identified.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2022)

Add to Collection

Article Electrochemistry

Towards Solid-State Magnesium Batteries: Ligand-Assisted Superionic Conductivity

Lasse N. Skov et al.

Summary: Solid-state inorganic magnesium batteries are considered as potential high energy storage devices of the future. In this study, magnesium borohydride tetrahydrofuran (THF) composites were used as solid-state electrolytes for magnesium batteries, and several compounds with high ionic conductivity were identified. A proof-of-concept rechargeable solid-state magnesium battery was assembled, showing stability and high discharge capacity.

BATTERIES & SUPERCAPS (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Amorphous Dual-Layer Coating: Enabling High Li-Ion Conductivity of Non-Sintered Garnet-Type Solid Electrolyte

Yuan Gao et al.

Summary: A novel strategy to achieve high Li+ ion conductivity of Garnet-type oxide Li6.4La3Zr1.4Ta0.6O12(LLZTO) without sintering is demonstrated by ball milling LLZTO together with LiBH4 to form a composite electrolyte with unique amorphous dual coating. The composite electrolyte displays an ultra-high Li+ transference number and enables long-term cycling of symmetric Li-Li cells.

ADVANCED FUNCTIONAL MATERIALS (2021)

Add to Collection

Article Electrochemistry

Editors' Choice-Quantifying the Impact of Charge Transport Bottlenecks in Composite Cathodes of All-Solid-State Batteries

Philip Minnmann et al.

Summary: This study analyzed the charge transport in composite cathodes composed of Li6PS5Cl and NCM-622, revealing correlations between effective conductivities, microstructure, and cell performance. Strategies for optimizing cell performance were developed and demonstrated through adjusting active material loadings and solid electrolyte particle size to tune electronic and ionic charge transport pathways.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Physical

Incorporation of Ammonia Borane Groups in the Lithium Borohydride Structure Enables Ultrafast Lithium Ion Conductivity at Room Temperature for Solid-State Batteries

Huan Liu et al.

CHEMISTRY OF MATERIALS (2020)

Add to Collection

Review Nanoscience & Nanotechnology

Designing solid-state electrolytes for safe, energy-dense batteries

Qing Zhao et al.

NATURE REVIEWS MATERIALS (2020)

Add to Collection

Article Energy & Fuels

Benchmarking the performance of all-solid-state lithium batteries

Simon Randau et al.

NATURE ENERGY (2020)

Add to Collection

Article Chemistry, Physical

Elucidating Reversible Electrochemical Redox of Li6PS5CI Solid Electrolyte

Darren H. S. Tan et al.

ACS ENERGY LETTERS (2019)

Add to Collection

Article Electrochemistry

The Indium-Lithium Electrode in Solid-State Lithium-Ion Batteries: Phase Formation, Redox Potentials, and Interface Stability

A. L. Santhosha et al.

BATTERIES & SUPERCAPS (2019)

Add to Collection

Review Chemistry, Physical

Solid Garnet Batteries

Ning Zhao et al.

JOULE (2019)

Add to Collection

Review Chemistry, Physical

Prospect and Reality of Ni-Rich Cathode for Commercialization

Junhyeok Kim et al.

ADVANCED ENERGY MATERIALS (2018)

Add to Collection

Article Chemistry, Physical

Fast Lithium-Ion Conduction in Atom-Deficient closo-Type Complex Hydride Solid Electrolytes

Sangryun Kim et al.

CHEMISTRY OF MATERIALS (2018)

Add to Collection

Review Chemistry, Physical

Review on solid electrolytes for all-solid-state lithium-ion batteries

Feng Zheng et al.

JOURNAL OF POWER SOURCES (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Solid Halide Electrolytes with High Lithium-Ion Conductivity for Application in 4 V Class Bulk-Type All-Solid-State Batteries

Tetsuya Asano et al.

ADVANCED MATERIALS (2018)

Add to Collection

Article Chemistry, Physical

Li3BO3-Li2CO3: Rationally Designed Buffering Phase for Sulfide All Solid-State Li-Ion Batteries

Sung Hoo Jung et al.

CHEMISTRY OF MATERIALS (2018)

Add to Collection

Article Nanoscience & Nanotechnology

Status, promises, and challenges of nanocomposite solid-state electrolytes for safe and high performance lithium batteries

J. Wan et al.

MATERIALS TODAY NANO (2018)

Add to Collection

Article Chemistry, Physical

A Lithium Amide-Borohydride Solid-State Electrolyte with Lithium-Ion Conductivities Comparable to Liquid Electrolytes

Yigang Yan et al.

ADVANCED ENERGY MATERIALS (2017)

Add to Collection

Review Nanoscience & Nanotechnology

Lithium battery chemistries enabled by solid-state electrolytes

Arumugam Manthiram et al.

NATURE REVIEWS MATERIALS (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review

Xin-Bing Cheng et al.

CHEMICAL REVIEWS (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Metal borohydrides and derivatives - synthesis, structure and properties

Mark Paskevicius et al.

CHEMICAL SOCIETY REVIEWS (2017)

Add to Collection

Editorial Material Energy & Fuels

A solid future for battery development

Juergen Janek et al.

NATURE ENERGY (2016)

Add to Collection

Article Energy & Fuels

High-power all-solid-state batteries using sulfide superionic conductors

Yuki Kato et al.

NATURE ENERGY (2016)

Add to Collection

Article Chemistry, Physical

Stable Interface Formation between TiS2 and LiBH4 in Bulk-Type All-Solid-State Lithium Batteries

Atsushi Unemoto et al.

CHEMISTRY OF MATERIALS (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Unparalleled lithium and sodium superionic conduction in solid electrolytes with large monovalent cage-like anions

Wan Si Tang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2015)

Add to Collection

Article Chemistry, Physical

Superionic Conduction of Sodium and Lithium in Anion-Mixed Hydroborates Na3BH4B12H12 and (Li0.7Na0.3)3BH4B12H12

Yolanda Sadikin et al.

ADVANCED ENERGY MATERIALS (2015)

Add to Collection

Article Chemistry, Physical

Bi-functional Li2B12H12 for energy storage and conversion applications: solid-state electrolyte and luminescent down-conversion dye

Joseph A. Teprovich et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Nanoconfined LiBH4 as a Fast Lithium Ion Conductor

Didier Blanchard et al.

ADVANCED FUNCTIONAL MATERIALS (2015)

Add to Collection

Article Chemistry, Physical

Fast Lithium Ion Conduction in Li2SnS3: Synthesis, Physicochemical Characterization, and Electronic Structure

Jacilynn A. Brant et al.

CHEMISTRY OF MATERIALS (2015)

Add to Collection

Article Chemistry, Multidisciplinary

A sulphide lithium super ion conductor is superior to liquid ion conductors for use in rechargeable batteries

Yoshikatsu Seino et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

Add to Collection

Review Chemistry, Physical

Lithium alloys and metal oxides as high-capacity anode materials for lithium-ion batteries

Chu Liang et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Thermal Stability of Li2B12H12 and its Role in the Decomposition of LiBH4

Mark P. Pitt et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Li10SnP2S12: An Affordable Lithium Superionic Conductor

Philipp Bron et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Superionic Conductivity in Lithium-Rich Anti-Perovskites

Yusheng Zhao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Add to Collection

Article Chemistry, Physical

A lithium superionic conductor

Noriaki Kamaya et al.

NATURE MATERIALS (2011)

Add to Collection

Review Chemistry, Physical

Lithium Fast-Ionic Conduction in Complex Hydrides: Review and Prospects

Motoaki Matsuo et al.

ADVANCED ENERGY MATERIALS (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Complex Hydrides with (BH4)- and (NH2)- Anions as New Lithium Fast-Ion Conductors

Motoaki Matsuo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Add to Collection

Article Chemistry, Multidisciplinary

Fast lithium ion conduction in garnet-type Li7La3Zr2O12

Ramaswamy Murugan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

Add to Collection

Article Physics, Applied

X-ray photoemission spectroscopy of nonmetallic materials:: Electronic structures of boron and BxOy

CW Ong et al.

JOURNAL OF APPLIED PHYSICS (2004)

Add to Collection

Review Multidisciplinary Sciences

Issues and challenges facing rechargeable lithium batteries

JM Tarascon et al.

NATURE (2001)

Add to Collection

© Peeref 2019-2024. All rights reserved.