Phytomediated-Assisted Preparation of Cerium Oxide Nanoparticles Using Plant Extracts and Assessment of Their Structural and Optical Properties

Cerium oxide nanoparticles were obtained using aqueous extracts of Chelidonium majus and Viscum album. X-ray diffractometry analysis confirmed the crystalline structure of the synthesized cerium oxide nanoparticles calcined at 600 degrees C. Scanning electron microscopy, UV-Vis reflectance and Raman spectroscopy, XPS, and fluorescence studies were utilized to interpret the morphological and optical properties of these nanoparticles. The STEM images revealed the spherical shape of the nanoparticles and that they were predominantly uniform in size. The optical band gap of our cerium nanoparticles was determined to be 3.3 and 3.0 eV from reflectance measurements using the Tauc plots. The nanoparticle sizes evaluated from the Raman band at 464 cm(-1) due to the F2g mode of the cubic fluorite structure of cerium oxide are close to those determined from the XRD and STEM data. The fluorescence results showed emission bands at 425, 446, 467, and 480 nm. The electronic absorption spectra have exhibited an absorption band around 325 nm. The antioxidant potential of the cerium oxide nanoparticles was estimated by DPPH scavenging assay.

Automated summary

Cerium oxide nanoparticles were synthesized using aqueous extracts of Chelidonium majus and Viscum album. Characterization techniques such as X-ray diffractometry, scanning electron microscopy, UV-Vis reflectance and Raman spectroscopy, XPS, and fluorescence were applied to study the morphology and optical properties of the nanoparticles. The results showed that the nanoparticles had a spherical shape with uniform size and exhibited specific absorption and emission bands. They also demonstrated antioxidant potential.