Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 48, Issue 47, Pages 17914-17922Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2023.01.269
Keywords
Activated carbon; Direct activation; N doping; H 2 storage; CO 2 storage
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In this study, nitrogen doped activated carbon (NAC) was synthesized from sustainable biomass by direct activation with the assistance of melamine. The obtained NAC showed enhanced adsorption capability for hydrogen and carbon dioxide, and the facile method of preparing NAC has potential for large-scaled production.
Activated carbon (AC), as an effective solid adsorbent, is extensively employed in H2 and CO2 storage. To enhance its adsorption capability and selectivity, it is necessary to increase its surface area and dope heteroatoms by a simple and environment-friendly method. In this work, nitrogen doped activated carbon (NAC) has been synthesized from sustainable biomass by direct activation with the assistance of melamine. The obtained NAC with 2.1 wt % N dopants possesses a high surface area (2477.27 m2/g) and pore volume (1.93 cm3/g). The NAC displayed enhanced H2 uptake capacity (2.29 wt% at 77 K, 1 bar and 0.83 wt% at 298 K, 100 bar) and adequate CO2 uptake capacity (2.85 mmol/g at 298 K, 1 bar and 4.49 mmol/g at 273 K, 1 bar). Activation mechanism with the assistance of melamine was proposed in accordance with the experimental data. The facile method of preparing NAC is potential for large-scaled production.& COPY; 2023 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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