4.7 Article

Tuning the hydrogen thermodynamics of NaAlH4 by encapsulation within a titanium shell

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

Surfactant Induced Synthesis of LiAlH4 and NaAlH4 Nanoparticles for Hydrogen Storage

Chulaluck Pratthana et al.

Summary: LiAlH4 and NaAlH4 are hindered by the lack of hydrogen reversibility and poor kinetics. Nanosizing has been suggested as a solution, but the synthesis of alanate nanoparticles has not been explored. In this study, a solvent evaporation method utilizing surfactants as stabilizers was used to assemble alanate nanoparticles, and the roles of surfactants in controlling particle size and morphology were determined.

APPLIED SCIENCES-BASEL (2022)

Review Chemistry, Physical

Modification of NaAlH4 properties using catalysts for solid-state hydrogen storage: A review

N. A. Ali et al.

Summary: Energy is an essential requirement in daily life, currently fulfilled by fossil fuels, but non-renewable fossil fuels are estimated to plummet rapidly in the next 20 years. The world will face an energy shortage and need a new environmental method of energy generation. Solid-state hydrogen storage is a key challenge, with NaAlH4 considered an attractive material that can be enhanced by adding catalysts and doping.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Materials Science, Multidisciplinary

A balance between catalysis and nanoconfinement towards enhanced hydrogen storage performance of NaAlH4

Wei Chen et al.

Summary: By utilizing Co-doped nanoporous carbon scaffolds as a structural host, this study successfully enhanced the hydrogen storage performance of NaAlH4 by removing Co nanoparticles to improve the catalytic effect and stability of nanoconfined spaces, achieving lower hydrogen storage temperature and higher cyclic stability.

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY (2021)

Article Chemistry, Physical

Kinetic and Fourier Transform Infrared Studies on the Thermal Decomposition of Sodium Hydride

Munemichi Kawaguchi

Summary: Experimental tests showed that sodium hydride has two hydrogen states at high temperatures, and specific Na-H bonds were observed using equipment such as FTIR. Postfired NaH at two different temperatures showed similar chemical bond information compared to prefired NaH.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Article Nanoscience & Nanotechnology

Nanoconfinement of Complex Borohydrides for Hydrogen Storage

Qiwen Lai et al.

Summary: The thermodynamic behavior of complex borohydrides confined in mesoporous hollow carbon spheres was investigated, showing no variation of equilibrium plateau pressure upon changes in the hydrogen sorption temperatures. This is interpreted as a result of the high pressure within the carbon nanopores, providing a means to control the thermodynamics of nanosized hydrides.

ACS APPLIED NANO MATERIALS (2021)

Review Energy & Fuels

Renewable hydrogen for the chemical industry

Nigel Rambhujun et al.

MRS ENERGY & SUSTAINABILITY (2020)

Review Chemistry, Physical

Hydrogen Storage for Mobility: A Review

Etienne Rivard et al.

MATERIALS (2019)

Article Chemistry, Physical

Anomalous H2 Desorption Rate of NaAlH4 Confined in Nitrogen-Doped Nanoporous Carbon Frameworks

Christopher L. Carr et al.

CHEMISTRY OF MATERIALS (2018)

Review Chemistry, Multidisciplinary

Nanostructured Metal Hydrides for Hydrogen Storage

Andreas Schneemann et al.

CHEMICAL REVIEWS (2018)

Article Chemistry, Physical

Nanoconfined lithium aluminium hydride (LiAlH4) and hydrogen reversibility

Lei Wang et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2017)

Article Electrochemistry

Failure mechanism of NaAlH4 negative electrodes in lithium cells

L. Silvestri et al.

ELECTROCHIMICA ACTA (2017)

Article Chemistry, Inorganic & Nuclear

Synthesis of LiAlH4 Nanoparticles Leading to a Single Hydrogen Release Step upon Ti Coating

Lei Wang et al.

INORGANICS (2017)

Article Chemistry, Multidisciplinary

Hydrogen Storage Materials for Mobile and Stationary Applications: Current State of the Art

Qiwen Lai et al.

CHEMSUSCHEM (2015)

Article Chemistry, Physical

Reactivity of Sodium Alanates in Lithium Batteries

L. Silvestri et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2015)

Article Chemistry, Physical

The catalyzed hydrogen sorption mechanism in alkali alanates

Zueleyha Oezlem Kocabas Atakli et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2015)

Article Chemistry, Physical

Significantly improved hydrogen storage properties of NaAlH4 catalyzed by Ce-based nanoparticles

Xiulin Fan et al.

JOURNAL OF MATERIALS CHEMISTRY A (2013)

Article Chemistry, Multidisciplinary

Core-Shell Strategy Leading to High Reversible Hydrogen Storage Capacity for NaBH4

Meganne L. Christian et al.

ACS NANO (2012)

Review Chemistry, Multidisciplinary

Proposed Mechanisms for the Catalytic Activity of Ti in NaAlH4

Terry J. Frankcombe

CHEMICAL REVIEWS (2012)

Review Chemistry, Multidisciplinary

Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications

Rajib Ghosh Chaudhuri et al.

CHEMICAL REVIEWS (2012)

Article Chemistry, Physical

Enhanced electroactivity for the oxygen reduction on Ni@Pt core-shell nanocatalysts

F. Godinez-Salomon et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2012)

Article Chemistry, Physical

Improved Dehydrogenation Properties of Ti-Doped LiAlH4: Role of Ti Precursors

Placidus B. Amama et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2012)

Review Materials Science, Multidisciplinary

Influence of nano-confinement on the thermodynamics and dehydrogenation kinetics of metal hydrides

John J. Vajo

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE (2011)

Article Chemistry, Physical

TEM characterization of pure and transition metal enhanced NaAlH4

Per Erik Vullum et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2011)

Article Chemistry, Multidisciplinary

Effect of Particle Size on Hydrogen Release from Sodium Alanate Nanoparticles

Tim Mueller et al.

ACS NANO (2010)

Article Chemistry, Physical

Thermodynamic Effects in Nanoscale NaAlH4

Wiebke Lohstroh et al.

CHEMPHYSCHEM (2010)

Article Chemistry, Physical

Kinetics of Hydrogen Desorption in NaAlH4 and Ti-Containing NaAlH4

Gopi Krishna Phani Dathar et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2010)

Article Chemistry, Physical

Confinement of NaAIH4 in Nanoporous Carbon: Impact on H2 Release, Reversibility, and Thermodynamics

Jinbao Gao et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2010)

Article Chemistry, Physical

Hydrogen desorption studies of NaAlH4 and LiAlH4 by in situ heating in an ESEM

Shane D. Beattie et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2009)

Article Chemistry, Physical

Microwave irradiation effects on reversible hydrogen desorption in sodium aluminum hydrides (NaAlH4)

Rahul Krishnan et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2009)

Article Physics, Multidisciplinary

Vibrational response of hydrogen-bonded interfacial water is dominated by intramolecular coupling

Maria Sovago et al.

PHYSICAL REVIEW LETTERS (2008)

Article Multidisciplinary Sciences

Vacancy-mediated dehydrogenation of sodium alanate

Hakan Gunaydin et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2008)

Review Multidisciplinary Sciences

Catalytic effect and reaction mechanism of Ti doped in NaAlH4: A review

Wang Qiang et al.

CHINESE SCIENCE BULLETIN (2008)

Article Chemistry, Physical

Dynamics of defects in alanates

R. Cantelli et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2007)

Article Materials Science, Multidisciplinary

Pressure-induced structural phase transition in NaAlH4

Ravhi S. Kumar et al.

PHYSICAL REVIEW B (2007)

Article Chemistry, Physical

Nature and role of Ti species in the hydrogenation of a NaH/Al mixture

Fang Fang et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2007)

Article Chemistry, Physical

Active Ti species in TiCl3-doped NaAlH4.: Mechanism for catalyst deactivation

Cornelis P. Balde et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2007)

Article Nanoscience & Nanotechnology

Advantage of TiF3 over TiCl3 as a dopant precursor to improve the thermodynamic property of Na3AlH6

Xiang-Dong Kang et al.

SCRIPTA MATERIALIA (2007)

Article Nanoscience & Nanotechnology

Monitoring of chemical reactions and point defect dynamics in sodium alanates

O. Palumbo et al.

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING (2006)

Article Chemistry, Multidisciplinary

Advanced hydrogen-storage materials based on Sc-, Ce-, and Pr-doped NaAlH4

Borislav Bogdanovic et al.

ADVANCED MATERIALS (2006)

Article Chemistry, Physical

Improved hydrogen storage of TiF3-doped NaAlH4

P Wang et al.

CHEMPHYSCHEM (2005)

Article Chemistry, Physical

Motion of point defects and monitoring of chemical reactions in sodium aluminium hydride

O Palumbo et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2005)

Article Materials Science, Multidisciplinary

Vacancy-mediated hydrogen desorption in NaAlH4 -: art. no. 165101

CM Araújo et al.

PHYSICAL REVIEW B (2005)

Article Materials Science, Multidisciplinary

Electron-microscopy studies of NaAlH4 with TiF3 additive:: hydrogen-cycling effects

CM Andrei et al.

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING (2005)

Article Chemistry, Physical

Point defect dynamics and evolution of chemical reactions in alanates by anelastic spectroscopy

O Palumbo et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2005)

Article Chemistry, Physical

Synchrotron X-ray and neutron diffraction studies of NaAlH4 containing Ti additives

HW Brinks et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2004)

Article Chemistry, Physical

Hydrogen desorption kinetics in transition metal modified NaAlH4

DL Anton

JOURNAL OF ALLOYS AND COMPOUNDS (2003)

Article Chemistry, Physical

Effect of Ti-catalyst content on the reversible hydrogen storage properties of the sodium alanates

G Sandrock et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2002)

Article Chemistry, Physical

Metal-doped sodium aluminium hydrides as potential new hydrogen storage materials

B Bogdanovic et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2000)

Article Chemistry, Physical

In-situ X-ray diffraction study of the decomposition of NaAlH4

KJ Gross et al.

JOURNAL OF ALLOYS AND COMPOUNDS (2000)