4.7 Article

Superatom Pruning by Diphosphine Ligands as a Chemical Scissor

Related references

Note: Only part of the references are listed.
Article Chemistry, Inorganic & Nuclear

Homoleptic Silver-Rich Trimetallic M20 Nanocluster

Wei-Jung Yen et al.

Summary: Two silver-rich M-20 alloy nanoclusters were synthesized and fully characterized. The position of Group 11 metals in the clusters was determined, and the presence of Cu-I atoms was found to improve the antioxidation ability.

INORGANIC CHEMISTRY (2022)

Article Chemistry, Physical

Alkynyl-Protected Ag12Cu4 Cluster with Aggregation-Induced Emission Enhancement

Guocheng Deng et al.

Summary: This study reports the synthesis and structure of a bimetallic AgCu cluster, Ag12Cu4, which exhibits crystallization-induced and aggregation-induced emission enhancement phenomena. The detailed structural analysis reveals the presence of abundant intercluster interactions, leading to strong photoluminescence enhancement in the solid state.

JOURNAL OF PHYSICAL CHEMISTRY C (2022)

Article Chemistry, Multidisciplinary

Compact accumulation of superatomic silver nanoclusters with an octahedral Ag6 core ligated by trithiane

Xun Cheng et al.

Summary: This article describes two superatomic solids and a homologous nanocluster, which exhibit aggregation-state-dependent absorption and fluorescence properties due to enhanced intercluster charge-transfer in the crystalline state.

NANOSCALE (2022)

Review Chemistry, Physical

Optical Properties and Excited-State Dynamics of Atomically Precise Gold Nanoclusters

Meng Zhou et al.

Summary: This review summarizes recent progress in the excited-state dynamics of atomically precise gold nanoclusters, discussing their electronic structure, relaxation pathways, and dynamics dependent on size, shape, structure, and composition. Quantum confinement effects, size dependence in exciton and electron dynamics, and the role of coherent oscillations in excited-state relaxation are also explored. The review provides insights into future directions in this area.

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 72 (2021)

Article Chemistry, Multidisciplinary

A Two-Electron Silver Superatom Isolated from Thermally Induced Internal Redox Reaction of A Silver(I) Hydride

Yu-Jie Zhong et al.

Summary: A dithiolate-stabilized two-electron silver nanocluster, Ag-10{S2P((OPr)-Pr-i)(2)}(8) (1), was successfully isolated without adding extra reducing agents. The cluster exhibits high fluorescence at ambient temperature, with emission of 1P(x)-> 1S nature according to TD-DFT calculations.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

Doping effect on the structure and properties of eight-electron silver nanoclusters

Yu-Jie Zhong et al.

Summary: The bimetallic compounds M-20 and M-21 were structurally characterized, showing that Cu(I) ions are randomly distributed on the outer positions. The UV-Vis absorption spectra of these bimetallic nanoclusters are almost identical to their homometallic relatives. Replacing the central Ag atom with Au results in a blue-shifted absorption in the trimetallic compound.

JOURNAL OF CHEMICAL PHYSICS (2021)

Review Chemistry, Multidisciplinary

Ligand exchange reactions on thiolate-protected gold nanoclusters

Yanan Wang et al.

Summary: Ligand exchange reaction is a versatile post-synthesis modification method that plays an important role in thiolate-protected gold nanoclusters by adjusting the gold-sulfur interface. This process follows a SN2-like mechanism, supported by both experiments and calculations. Ligand exchange reaction can impart different functionalities and properties to gold nanoclusters.

NANOSCALE ADVANCES (2021)

Review Chemistry, Multidisciplinary

Tailoring silver nanoclusters via doping: advances and opportunities

Jie Yang et al.

Summary: Doping with hetero metal atoms has shown advancements in tailoring the structures and properties of silver nanoclusters. The doping affects the stability and charge state evolution of Ag NCs, while also enhancing their photoluminescence performance and catalytic activity.

NANOSCALE ADVANCES (2021)

Article Chemistry, Multidisciplinary

All-Carboxylate-Protected Superatomic Silver Nanocluster with an Unprecedented Rhombohedral Ag8 Core

Kuan-Guan Liu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

Spontaneous Resolution of Chiral Multi-Thiolate-Protected Ag30 Nanoclusters

Jia-Hong Huang et al.

ACS CENTRAL SCIENCE (2020)

Review Biotechnology & Applied Microbiology

Ultrasmall Au and Ag Nanoclusters for Biomedical Applications: A Review

Jia Tang et al.

FRONTIERS IN BIOENGINEERING AND BIOTECHNOLOGY (2020)

Article Chemistry, Inorganic & Nuclear

[Ag7(H){S2CC(CN)2}6]6-: An Anionic Heptanuclear Silver Hydride Cluster Compound Stabilized by Dithiolate Ligands

Ping-Kuei Liao et al.

JOURNAL OF CLUSTER SCIENCE (2019)

Article Chemistry, Multidisciplinary

Atomically Precise Metal Nanoclusters for Catalysis

Xiangsha Du et al.

ACS NANO (2019)

Article Chemistry, Multidisciplinary

Real Time Monitoring of the Dynamic Intracluster Diffusion of Single Gold Atoms into Silver Nanoclusters

Kaiyuan Zheng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Inorganic & Nuclear

Cluster-to-duster transformation among Au6, Au8 and Au11 nanoclusters

Xiuqing Ren et al.

DALTON TRANSACTIONS (2018)

Article Chemistry, Multidisciplinary

Atomically Precise Site-Specific Tailoring and Directional Assembly of Superatomic Silver Nanoclusters

Zhao-Yang Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Multidisciplinary Sciences

Trapping an octahedral Ag-6 kernel in a seven-fold symmetric Ag-56 nanowheel

Zhi Wang et al.

NATURE COMMUNICATIONS (2018)

Review Chemistry, Multidisciplinary

Structurally Precise Dichalcogenolate-Protected Copper and Silver Superatomic Nanoclusters and Their Alloys

Sachil Sharma et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Review Chemistry, Multidisciplinary

Customizing the Structure, Composition, and Properties of Alloy Nanoclusters by Metal Exchange

Shuxin Wang et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Article Chemistry, Multidisciplinary

Alkynyl-protected silver nanoclusters featuring an anticuboctahedral kernel

Shang-Fu Yuan et al.

NANOSCALE (2017)

Article Chemistry, Multidisciplinary

Multi-ligand-directed synthesis of chiral silver nanoclusters

Xuejuan Zou et al.

NANOSCALE (2017)

Article Multidisciplinary Sciences

Molecular surgery on a 23-gold-atom nanoparticle

Qi Li et al.

SCIENCE ADVANCES (2017)

Article Chemistry, Multidisciplinary

Eight-Electron Silver and Mixed Gold/Silver Nanoclusters Stabilized by Selenium Donor Ligands

Wan-Ting Chang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

[Ag20{S2P(OR)2}12]: A Superatom Complex with a Chiral Metallic Core and High Potential for Isomerism

Rajendra S. Dhayal et al.

CHEMISTRY-A EUROPEAN JOURNAL (2016)

Article Chemistry, Inorganic & Nuclear

A Twelve-Coordinated Iodide in a Cuboctahedral Silver(I) Skeleton

Jian-Hong Liao et al.

INORGANIC CHEMISTRY (2014)

Article Chemistry, Multidisciplinary

Crystal structure of a luminescent thiolated Ag nanocluster with an octahedral Ag-6(4+) core

Huayan Yang et al.

CHEMICAL COMMUNICATIONS (2013)

Article Chemistry, Multidisciplinary

A discrete octahedrally shaped [Ag-6](4+) cluster encapsulated within silicotungstate ligands

Yuji Kikukawa et al.

CHEMICAL COMMUNICATIONS (2013)

Article Chemistry, Inorganic & Nuclear

A Copper(I) Homocubane Collapses to a Tetracapped Tetrahedron Upon Hydride Insertion

Ping-Kuei Liao et al.

INORGANIC CHEMISTRY (2011)

Article Chemistry, Multidisciplinary

Anion-templated syntheses of octanuclear silver clusters from a silver dithiophosphate chain

C. W. Liu et al.

CHEMICAL COMMUNICATIONS (2010)

Article Chemistry, Inorganic & Nuclear

Stable Silver(I) Hydride Complexes Supported by Diselenophosphate Ligands

C. W. Liu et al.

INORGANIC CHEMISTRY (2010)

Article Chemistry, Inorganic & Nuclear

A Polynuclear d10-d10 Metal Complex with Unusual Near-Infrared Luminescence and High Thermal Stability

Chengyang Yue et al.

INORGANIC CHEMISTRY (2009)

Article Chemistry, Multidisciplinary

A short history of SHELX

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2008)

Article Chemistry, Inorganic & Nuclear

Octahedral hexanuclear silver(I) and copper(I) ferrocenylacetylide complexes

QH Wei et al.

INORGANIC CHEMISTRY COMMUNICATIONS (2004)