Journal
INORGANIC CHEMISTRY
Volume 62, Issue 19, Pages 7150-7154Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.3c00558
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Neutral triple-decker iron and cobalt complexes with a bridging 1,2-diboratabenzene ligand were synthesized by reacting a dilithium 1,2-diboratabenzene reagent with [Cp*FeCl]2 and [Cp*CoCl]2, respectively. These complexes are the first examples of the ligand bridging two metals, although 1,2-diboratabenzene metal complexes are already known.
Neutral triple-decker iron and cobalt complexes with a bridging 1,2-diboratabenzene ligand were accessed by reactions of a dilithium 1,2-diboratabenzene reagent with [Cp*FeCl]2 and [Cp*CoCl]2, respectively. While 1,2-diboratabenzene metal complexes are known, these represent the first examples of the ligand bridging two metals.
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