Journal
CERAMICS INTERNATIONAL
Volume 41, Issue 9, Pages 11770-11775Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2015.05.144
Keywords
SiO2 shells; Three-dimensionally ordered macroporous materials; Upconversion emission; Bi2Ti2O7:Er3+, Yb3+
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Funding
- Reserve Talents Project of Yunnan Province [2012HB068]
- Applied Basic Research Program of Yunnan Province [2014FB127]
- Talent Youth Science Foundation of College of Materials Science and Technology, Kunming University of Science and Technology [20140205]
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In this paper, a simple effective approach has been developed to enhance upconversion emission of three-dimensionally ordered macroporous materials, which is attributed to formation of silica shell around surface of three-dimensionally ordered macroporous materials. This approach involves the preparation of Bi2Ti2O7:Er3+, Yb3+ three-dimensionally ordered macroporous materials and the formation of amorphous SiO2 shell on the macroporous surfaces of three-dimensionally ordered macroporous materials. The influence of silica shell on the upconversion emission of Er3+ ions was investigated, and the enhanced upconversion emission was observed in the Bi2Ti2O7:Er3+, Yb3+ three-dimensionally ordered macroporous materials owing to the suppression of surface quenching effect caused by the formation of silica shells. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
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