4.7 Article

Enhanced upconversion emission of three dimensionally ordered macroporous films Bi2Ti2O7:Er3+, Yb3+ with silica shell

Journal

CERAMICS INTERNATIONAL
Volume 41, Issue 9, Pages 11770-11775

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2015.05.144

Keywords

SiO2 shells; Three-dimensionally ordered macroporous materials; Upconversion emission; Bi2Ti2O7:Er3+, Yb3+

Funding

  1. Reserve Talents Project of Yunnan Province [2012HB068]
  2. Applied Basic Research Program of Yunnan Province [2014FB127]
  3. Talent Youth Science Foundation of College of Materials Science and Technology, Kunming University of Science and Technology [20140205]

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In this paper, a simple effective approach has been developed to enhance upconversion emission of three-dimensionally ordered macroporous materials, which is attributed to formation of silica shell around surface of three-dimensionally ordered macroporous materials. This approach involves the preparation of Bi2Ti2O7:Er3+, Yb3+ three-dimensionally ordered macroporous materials and the formation of amorphous SiO2 shell on the macroporous surfaces of three-dimensionally ordered macroporous materials. The influence of silica shell on the upconversion emission of Er3+ ions was investigated, and the enhanced upconversion emission was observed in the Bi2Ti2O7:Er3+, Yb3+ three-dimensionally ordered macroporous materials owing to the suppression of surface quenching effect caused by the formation of silica shells. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

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