4.7 Article

Design and Analysis of Highly Sensitive Plasmonic Sensor Based on 2-D Inorganic Ti-MXene and SrTiO3 Interlayer

Journal

IEEE SENSORS JOURNAL
Volume 23, Issue 12, Pages 12727-12735

Publisher

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC
DOI: 10.1109/JSEN.2023.3270133

Keywords

Sensors; Sensitivity; Refractive index; Biosensors; Reflectivity; Metals; Molecular biophysics; Biosensor; Kretschmann configuration; MXene; SrTiO3; surface plasmon resonance (SPR)

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In this article, a new type of surface plasmon resonance (SPR) sensor is proposed, which uses SrTiO3 and MXene as interlayers to improve the sensitivity and performance of conventional SPR sensors. Through optimization design, the theoretical results show that the proposed sensor has high sensitivity, accuracy, and a wide detection range, indicating great potential in diagnostic applications and portable biosensors.
Using appropriate interlayers, the sensitivity and performance of conventional surface plasmon resonance (SPR) sensors can be improved in the Kretschmann configuration. In this article, nano-layered SrTiO3 is proposed as an interlayer, which besides protecting silver from oxidation, due to the high refractive index and zero loss in the visible region, increases field intensity and sensitivity. The use of the Ti(3)C(2)Tx MXene layer also leads to better adsorption of biomolecules due to high binding energies and large area. Using structural engineering, we optimized the physical parameters of the device. The theoretical results show that the proposed sensor has a sensitivity of 301.2 degrees /RIU which is 164% higher than the Ag-only sensor, a detection accuracy (DA) of 0.119 degrees(-1), a quality factor of 35.84 RIU-1, a detection range of 1.33-1.3377 and near-zero minimum reflectance for 43 nm Ag, 12 nm SrTiO3, and a monolayer of MXene. Therefore, the proposed sensor is promising to be used in diagnostic applications and portable biosensors. Although, we can reach the highest sensitivity and quality factor of 438.4 degrees/RIU and 103.9 RIU-1 for 48 nm Ag and 13 nm SrTiO3 without any MXene layer for non-bio (other) applications. However, using 2-D materials such as MXene increases the adsorption efficiency of the biosensor. Furthermore, by using the reflectance intensity difference method, we reach the sensitivity of 8000%/RIU.

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