4.8 Article

High-Performance Sodium Ion Batteries Based on a 3D Anode from Nitrogen-Doped Graphene Foams

Journal

ADVANCED MATERIALS
Volume 27, Issue 12, Pages 2042-2048

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201405370

Keywords

3D graphene; anodes; nitrogen-doping; sodium ion batteries

Funding

  1. AFOSR [FA9550-12-1-0037, FA-9550-12-1-0069]
  2. NSF [NSF-CMMI-1000768, NSF-CMMI-1400274, NSF-DMR-1106160]
  3. Auto CRC
  4. Division Of Materials Research
  5. Direct For Mathematical & Physical Scien [1106160] Funding Source: National Science Foundation
  6. Div Of Civil, Mechanical, & Manufact Inn
  7. Directorate For Engineering [1400274] Funding Source: National Science Foundation
  8. Div Of Civil, Mechanical, & Manufact Inn
  9. Directorate For Engineering [1363123] Funding Source: National Science Foundation

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A 3D N-doped graphene foam with a 6.8 at% nitrogen content is prepared by annealing a freeze-dried graphene oxide foam in ammonia. It is used as an anode in sodium ion batteries to deliver a high initial reversible capacity of 852.6 mA h g -1 at 1 C between 0.02 and 3 V with a long-term retention of 69.7% after 150 cycles.

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