Insight into influence of process parameters on co-pyrolysis interaction between Yulin coal and waste tire via rapid infrared heating

Co-pyrolysis of coal and waste tire is an important route to realize their clean and efficient utilization. To study the interaction during co-pyrolysis, the rapid infrared-heated fixed-bed reactor was adapted to explore the effects of heating rate, pyrolysis temperature and mixing ratio on the products distribution, tar quality and compositions during the co-pyrolysis of Yulin coal (YL) and waste tire (WT), and the interaction mechanism was also explored. The results show that heating rate, mixing ratio and pyrolysis temperature exerted the synergistic effect during co-pyrolysis. High heating rate was beneficial to the interaction of coal and waste tire, and the maximum positive synergistic effect of tar production was obtained at the heating rate of 10 degrees C/s. The content of light tar (boiling point < 360 degrees C) in co-pyrolysis tar increased gradually with amount of WT added in blends. When the mixing ratio of YL/WT was 1:1, the most remarkable difference between the experimental and calculated contents of light tar in tar suggested obvious positive synergy among the blended samples. In addition, gas production was remarkably suppressed during co-pyrolysis. It is analyzed that H-rich free radicals like center dot H or center dot CH3 produced from the cleavage of aliphatic hydrocarbon chains of WT or other reactions like cyclization stabilize the free radicals from coal pyrolysis and contribute to the improved tar quality and the synergy during co-pyrolysis.

Automated summary

The co-pyrolysis of coal and waste tire is a significant method for their clean and efficient utilization. By using a rapid infrared-heated fixed-bed reactor, the effects of heating rate, pyrolysis temperature, and mixing ratio on the products distribution, tar quality, and compositions during the co-pyrolysis of Yulin coal (YL) and waste tire (WT) were investigated. The results revealed that the heating rate, mixing ratio, and pyrolysis temperature exerted a synergistic effect during co-pyrolysis. Moreover, the addition of WT in blends led to an increase in the content of light tar in the co-pyrolysis tar. Gas production was also suppressed during co-pyrolysis.