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A technical review on coke rate and quality in low-carbon blast furnace ironmaking

Journal

FUEL
Volume 336, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2022.127077

Keywords

Blast furnace ironmaking; Metallurgical coke; Hydrogen reduction; GHG emissions; Biomass; Sustainability

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Blast furnace technology remains the main ironmaking route, accounting for 70% of global share. Reducing fossil carbon consumption and CO2 emissions in blast furnace operations is crucial for decarbonizing steelmaking. Various solutions such as introducing renewable carbon-based materials, using hydrogen-enriched reducing gases, oxygen enrichment, and carbon capture and storage/utilization have been considered. Improving the hydrogen-to-carbon replacement ratio is key to enhancing the sustainability of blast furnace operations. This paper reviews the impact of alternative reducing agents on coke gasification behavior, degradation mechanism, and consumption rate in blast furnaces.
The blast furnace technology is still the main ironmaking route with a current global share of 70%. Reduction of fossil carbon consumption and CO2 emissions in blast furnace operations are essential for the decarbonization of steelmaking. Potential solutions such as introducing renewable carbon-based materials (torrefied biomass, charcoal), using hydrogen-enriched reducing gases (i.e., hydrogen gas, coke oven gas, reformed coke oven gas, green methane), oxygen enrichment with top gas recycling, and carbon capture and storage/utilization have been considered to decrease emissions. The enhanced sustainability of blast furnace operations depends pri-marily on improving the hydrogen-to-carbon replacement ratio. Hydrogen is an effective reducing agent, pro-ducing steam during the reduction of ferrous burden. The replacement of coke and PCI with hydrogen leads to reduced fuel rates and CO2 emissions. Although implementing the innovative ironmaking solutions reduces coke and coal consumption, coke cannot be replaced entirely as it plays an irreplaceable role as a mechanical support network and the permeable layer for gas movement in the blast furnace. The injection of alternative reducing agents into the blast furnace alters the reaction environment by changing gas composition and temperature. Therefore, understanding the impacts of new reaction conditions on coke rate and quality requirements is important to both coal producers and steel manufacturers. This paper reviews the current understanding of how the introduction of alternative reducing agents into the blast furnace influences the gasification behavior, degradation mechanism, and consumption rate of coke. The review also identifies the knowledge gaps and future research opportunities in the field.

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